********************* Core Excitation Data ******************** **************** A.P. Hitchcock & D.C. Mancini **************** * * Formula: H2Si(NtBuCH=CHNtBu) * Name: unsaturated SiH2 silylene * Edge: Si 2p * Alpha Formula: C10H22N2Si * Data Source: Hitchcock * Filename: uq-0sill.os * Ref. Code: UH+98 * Write Date: 08/05/98 * Reference: Oranometallics 17 (1998) 2352. * Source and Purity: Denk, distilled under vacuum * Acquisition Mode: EELS, 2 deg, 2500eV CRE mode, 0.7eV fwhm *-------------------------------------------------------------- * No. of Spectra: 2 name1- 0uql6 name2- 0uql.os * E (eV) Raw data Osc. Str. per atom (E-2) *-------------------------------------------------------------- 9.194870E+01 3.512516E+04 -7.562873E-02 9.220013E+01 3.477709E+04 1.310087E-01 9.245155E+01 3.415813E+04 -3.305661E-03 9.270299E+01 3.393580E+04 -1.487725E-02 9.295441E+01 3.345336E+04 -7.539517E-02 9.320584E+01 3.321748E+04 -2.167230E-02 9.345728E+01 3.302234E+04 8.128634E-02 9.369727E+01 3.258636E+04 7.260419E-02 9.394870E+01 3.219678E+04 -5.176470E-02 9.420013E+01 3.170165E+04 -3.531249E-02 9.445156E+01 3.152714E+04 1.568090E-02 9.470299E+01 3.118581E+04 -1.061375E-01 9.495442E+01 3.088181E+04 -5.333545E-02 9.520585E+01 3.050334E+04 3.640319E-02 9.545728E+01 3.017625E+04 3.710658E-02 9.569728E+01 2.997175E+04 3.463890E-02 9.594871E+01 2.971210E+04 2.168008E-02 9.620013E+01 2.941955E+04 2.031267E-02 9.645157E+01 2.907477E+04 3.274948E-02 9.670300E+01 2.877017E+04 -4.762414E-02 9.695442E+01 2.878119E+04 3.545446E-02 9.720586E+01 2.834808E+04 -6.245412E-03 9.745728E+01 2.804167E+04 6.507575E-03 9.769728E+01 2.776188E+04 -5.657422E-03 9.794872E+01 2.748684E+04 4.006702E-02 9.820014E+01 2.715849E+04 9.371080E-02 9.845157E+01 2.683656E+04 -1.211924E-01 9.870300E+01 2.650987E+04 9.659175E-03 9.895443E+01 2.636184E+04 -2.914240E-02 9.920586E+01 2.595078E+04 -4.991681E-02 9.945729E+01 2.561789E+04 -5.939160E-02 9.969729E+01 2.559069E+04 -9.392514E-03 9.994872E+01 2.546500E+04 3.948976E-02 1.002001E+02 2.527351E+04 2.995742E-02 1.004516E+02 2.497646E+04 7.202785E-02 1.007030E+02 2.477045E+04 2.773747E-03 1.009544E+02 2.428730E+04 -2.148661E-02 1.012059E+02 2.413253E+04 -2.668878E-02 1.014573E+02 2.410591E+04 1.229891E-01 1.016973E+02 2.374652E+04 -1.647820E-02 1.018566E+02 2.365261E+04 3.408268E-03 1.020051E+02 2.365255E+04 7.321408E-02 1.021537E+02 2.373065E+04 3.013280E-01 1.023023E+02 2.405837E+04 5.277508E-01 1.024508E+02 2.456579E+04 1.029408E+00 1.025994E+02 2.492904E+04 1.492961E+00 1.027480E+02 2.528765E+04 2.031581E+00 1.028966E+02 2.603225E+04 2.558009E+00 1.030451E+02 2.666049E+04 3.260931E+00 1.031937E+02 2.727299E+04 4.023620E+00 1.033423E+02 2.805494E+04 4.868301E+00 1.034908E+02 2.858373E+04 5.537300E+00 1.036394E+02 2.880189E+04 5.835862E+00 1.037880E+02 2.870623E+04 6.018093E+00 1.039366E+02 2.829675E+04 5.723363E+00 1.040966E+02 2.761907E+04 5.272812E+00 1.042451E+02 2.700662E+04 4.788823E+00 1.043937E+02 2.645907E+04 4.227582E+00 1.045423E+02 2.590585E+04 3.922328E+00 1.046908E+02 2.568447E+04 3.685180E+00 1.048394E+02 2.537355E+04 3.513454E+00 1.049880E+02 2.497898E+04 3.433233E+00 1.051366E+02 2.488056E+04 3.447634E+00 1.052851E+02 2.483330E+04 3.441782E+00 1.054337E+02 2.499837E+04 3.502288E+00 1.055823E+02 2.501853E+04 3.641348E+00 1.057309E+02 2.481260E+04 3.574778E+00 1.058794E+02 2.474754E+04 3.621754E+00 1.060280E+02 2.462001E+04 3.617306E+00 1.061766E+02 2.458864E+04 3.674120E+00 1.063251E+02 2.432157E+04 3.549312E+00 1.064737E+02 2.404017E+04 3.511449E+00 1.066337E+02 2.392524E+04 3.523224E+00 1.067823E+02 2.394331E+04 3.430201E+00 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1.831152E+04 3.328040E+00 1.167066E+02 1.805692E+04 3.246654E+00 1.169580E+02 1.812888E+04 3.317976E+00 1.171980E+02 1.796230E+04 3.381603E+00 1.174494E+02 1.771841E+04 3.379777E+00 1.177009E+02 1.776442E+04 3.459299E+00 1.179523E+02 1.769602E+04 3.435936E+00 1.182037E+02 1.758171E+04 3.645043E+00 1.184551E+02 1.767269E+04 3.657878E+00 1.187066E+02 1.753783E+04 3.680056E+00 1.189580E+02 1.759187E+04 3.748156E+00 1.191980E+02 1.734009E+04 3.706530E+00 1.194494E+02 1.732682E+04 3.820182E+00 1.197009E+02 1.745562E+04 3.879138E+00 1.199523E+02 1.728465E+04 3.948638E+00 1.202037E+02 1.713425E+04 3.932613E+00 1.204551E+02 1.716566E+04 4.029404E+00 1.207066E+02 1.737278E+04 4.118436E+00 1.209466E+02 1.726936E+04 4.153349E+00 1.211980E+02 1.712632E+04 4.184856E+00 1.214494E+02 1.700964E+04 4.347646E+00 1.217009E+02 1.704571E+04 4.343222E+00 1.219523E+02 1.699184E+04 4.421726E+00 1.222037E+02 1.692204E+04 4.498144E+00 1.224552E+02 1.696662E+04 4.471622E+00 1.227066E+02 1.701926E+04 4.616198E+00 1.229466E+02 1.696552E+04 4.673015E+00 1.231980E+02 1.683790E+04 4.655669E+00 1.234494E+02 1.702726E+04 4.721811E+00 1.237009E+02 1.686520E+04 4.818755E+00 1.239523E+02 1.681061E+04 4.866081E+00 1.242037E+02 1.661917E+04 4.882492E+00 1.244552E+02 1.655684E+04 4.874051E+00 1.247066E+02 1.660671E+04 4.918057E+00 1.249466E+02 1.662888E+04 5.050552E+00 1.251980E+02 1.661161E+04 5.056502E+00 1.254494E+02 1.661850E+04 5.081190E+00 1.257009E+02 1.651269E+04 5.141365E+00 1.259523E+02 1.648866E+04 5.147275E+00 1.262037E+02 1.646821E+04 5.153820E+00 1.264552E+02 1.628319E+04 5.118727E+00 1.267066E+02 1.633060E+04 5.305805E+00 1.269466E+02 1.618543E+04 5.228241E+00 1.271980E+02 1.615969E+04 5.206715E+00 1.274494E+02 1.602674E+04 5.175172E+00 1.277009E+02 1.606211E+04 5.298317E+00 1.279523E+02 1.602528E+04 5.212472E+00 1.282037E+02 1.602016E+04 5.349859E+00 1.284552E+02 1.591233E+04 5.241350E+00 1.287066E+02 1.576621E+04 5.375748E+00 1.289466E+02 1.566941E+04 5.330395E+00 1.291980E+02 1.547544E+04 5.239600E+00 1.294495E+02 1.538363E+04 5.264827E+00 1.297009E+02 1.541199E+04 5.153013E+00 1.299523E+02 1.534277E+04 5.181175E+00 1.302038E+02 1.527781E+04 5.184186E+00 1.304552E+02 1.520448E+04 5.190098E+00 1.307066E+02 1.519723E+04 5.128236E+00 1.309466E+02 1.502613E+04 5.104760E+00 1.311980E+02 1.498971E+04 5.101103E+00 1.314495E+02 1.479893E+04 5.068600E+00 1.317009E+02 1.484279E+04 5.134208E+00 1.319523E+02 1.456430E+04 5.026095E+00 1.322038E+02 1.441789E+04 4.978178E+00 1.324552E+02 1.445849E+04 5.011473E+00 1.327066E+02 1.450629E+04 4.984522E+00 1.329466E+02 1.451173E+04 4.979221E+00 1.331980E+02 1.429504E+04 4.920263E+00 1.334495E+02 1.415632E+04 4.927730E+00 1.337009E+02 1.404845E+04 4.952276E+00 1.339523E+02 1.383961E+04 4.893763E+00 1.342038E+02 1.400777E+04 4.868222E+00 1.344552E+02 1.396132E+04 4.874377E+00 1.347066E+02 1.365400E+04 4.796229E+00 1.349466E+02 1.356106E+04 4.715166E+00 1.351980E+02 1.359300E+04 4.788913E+00 1.354495E+02 1.369494E+04 4.827656E+00 1.357009E+02 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