********************* Core Excitation Data ******************** **************** A.P. Hitchcock & D.C. Mancini **************** * * Formula: Si(NtBuCH2CH2NtBu) * Name: saturated silylene * Edge: Si 2p * Alpha Formula: C10H22N2Si * Data Source: Hitchcock * Filename: ut-0sill.os * Ref. Code: UH+98 * Write Date: 08/05/98 * Reference: Organometallics 17 (1998) 2352. * Source and Purity: Denk, sublimed under argon * Acquisition Mode: EELS, 2 deg, 2500eV CRE mode, 0.7eV fwhm *-------------------------------------------------------------- * No. of Spectra: 2 name1- 0utl10 name2- 0utl.os * E (eV) Raw data Osc. Str. per atom (E-2) *-------------------------------------------------------------- 9.043453E+01 3.119600E+04 -7.790668E-02 9.062894E+01 3.070500E+04 -2.354610E-03 9.083479E+01 3.039900E+04 2.175209E-02 9.102919E+01 3.011200E+04 -1.185367E-02 9.123503E+01 2.993000E+04 1.573800E-02 9.142944E+01 2.980900E+04 3.485148E-02 9.163528E+01 2.953200E+04 3.861367E-02 9.182969E+01 2.919100E+04 1.164807E-03 9.203553E+01 2.921000E+04 1.561279E-02 9.222993E+01 2.884300E+04 2.393702E-02 9.243578E+01 2.838900E+04 -5.845225E-03 9.263019E+01 2.850900E+04 1.493733E-02 9.283603E+01 2.796200E+04 -7.164298E-02 9.303043E+01 2.798800E+04 5.686907E-02 9.323628E+01 2.772000E+04 -1.820737E-02 9.343069E+01 2.717800E+04 -1.540495E-02 9.363653E+01 2.720900E+04 3.820651E-02 9.383093E+01 2.679600E+04 -8.307353E-02 9.403678E+01 2.665300E+04 -2.791592E-02 9.423119E+01 2.672500E+04 6.578433E-02 9.443703E+01 2.640700E+04 2.247055E-02 9.463143E+01 2.592500E+04 -6.877612E-03 9.483728E+01 2.593500E+04 -1.167536E-02 9.503168E+01 2.563800E+04 5.665284E-02 9.523753E+01 2.518000E+04 -7.162671E-02 9.543193E+01 2.533900E+04 1.184057E-02 9.563778E+01 2.504800E+04 -3.264986E-02 9.583218E+01 2.483500E+04 -4.831475E-02 9.603802E+01 2.436100E+04 3.279052E-02 9.623243E+01 2.441300E+04 -1.293988E-02 9.643828E+01 2.428400E+04 7.810890E-02 9.663268E+01 2.405200E+04 3.181221E-02 9.683852E+01 2.362000E+04 3.257197E-02 9.703293E+01 2.368400E+04 4.426394E-02 9.723878E+01 2.318800E+04 -2.673820E-02 9.743318E+01 2.297400E+04 -3.208323E-02 9.763902E+01 2.292800E+04 -6.001133E-02 9.783343E+01 2.271200E+04 -4.387418E-02 9.803928E+01 2.258400E+04 -9.097978E-03 9.823368E+01 2.254200E+04 -3.424800E-02 9.843952E+01 2.230200E+04 -4.730276E-02 9.852917E+01 2.225700E+04 -1.973133E-02 9.863209E+01 2.234400E+04 6.471741E-03 9.873501E+01 2.200600E+04 2.663007E-02 9.883793E+01 2.214900E+04 4.243820E-02 9.892942E+01 2.209500E+04 2.336752E-02 9.903234E+01 2.203400E+04 -1.221495E-02 9.913526E+01 2.210200E+04 2.742068E-02 9.923818E+01 2.153300E+04 -1.592503E-02 9.932967E+01 2.158900E+04 -5.632486E-03 9.943259E+01 2.161200E+04 -2.021059E-02 9.953551E+01 2.161100E+04 2.160466E-02 9.963843E+01 2.138500E+04 3.267491E-03 9.972992E+01 2.126300E+04 -1.021278E-02 9.983284E+01 2.134100E+04 4.641941E-02 9.993576E+01 2.087600E+04 2.467695E-02 1.000387E+02 2.120800E+04 1.246749E-01 1.001302E+02 2.113400E+04 6.357595E-02 1.002331E+02 2.099200E+04 9.464968E-02 1.003360E+02 2.116000E+04 1.316749E-01 1.004389E+02 2.114200E+04 2.340738E-01 1.005304E+02 2.104800E+04 2.264352E-01 1.006333E+02 2.089800E+04 2.710558E-01 1.007363E+02 2.095200E+04 2.637031E-01 1.008392E+02 2.063500E+04 3.099920E-01 1.009307E+02 2.103500E+04 3.480565E-01 1.010336E+02 2.080700E+04 3.195486E-01 1.011365E+02 2.074500E+04 3.113040E-01 1.012394E+02 2.067300E+04 3.120601E-01 1.013309E+02 2.053600E+04 2.566991E-01 1.014338E+02 2.023400E+04 2.146971E-01 1.015368E+02 2.009800E+04 1.704813E-01 1.016397E+02 2.017400E+04 1.655216E-01 1.017312E+02 1.992300E+04 1.380099E-01 1.018341E+02 1.980200E+04 1.357843E-01 1.019370E+02 1.980000E+04 1.414097E-01 1.020399E+02 1.962600E+04 1.526094E-01 1.021314E+02 1.936400E+04 1.715367E-01 1.022343E+02 1.939200E+04 3.300909E-01 1.023373E+02 1.970500E+04 4.980401E-01 1.024287E+02 1.988400E+04 6.128993E-01 1.025317E+02 1.981400E+04 7.044845E-01 1.026346E+02 2.030400E+04 9.335410E-01 1.027375E+02 2.036300E+04 1.025479E+00 1.028290E+02 2.082400E+04 1.172719E+00 1.029319E+02 2.041600E+04 1.215839E+00 1.030348E+02 2.092900E+04 1.415139E+00 1.031378E+02 2.072500E+04 1.513712E+00 1.032292E+02 2.104800E+04 1.677414E+00 1.033322E+02 2.119900E+04 1.859381E+00 1.034351E+02 2.136400E+04 1.980371E+00 1.035380E+02 2.149700E+04 2.003816E+00 1.036295E+02 2.138600E+04 2.030289E+00 1.037324E+02 2.178100E+04 2.093064E+00 1.038353E+02 2.134400E+04 1.928374E+00 1.039383E+02 2.123600E+04 1.946673E+00 1.040297E+02 2.091300E+04 1.853264E+00 1.041327E+02 2.032200E+04 1.785473E+00 1.042356E+02 2.068600E+04 1.784359E+00 1.043385E+02 2.034400E+04 1.782219E+00 1.044300E+02 2.017700E+04 1.786974E+00 1.045329E+02 2.018800E+04 1.811214E+00 1.046358E+02 2.046400E+04 1.848355E+00 1.047388E+02 2.010800E+04 1.866457E+00 1.048302E+02 2.028100E+04 1.967517E+00 1.049332E+02 1.977200E+04 1.924095E+00 1.050361E+02 1.990700E+04 1.923734E+00 1.051390E+02 1.996800E+04 1.960265E+00 1.052305E+02 2.047200E+04 2.082501E+00 1.053334E+02 1.999200E+04 2.042463E+00 1.054363E+02 2.030900E+04 2.094937E+00 1.055393E+02 2.010500E+04 2.077256E+00 1.056307E+02 2.004300E+04 2.118100E+00 1.057337E+02 1.993200E+04 2.098177E+00 1.058366E+02 1.973800E+04 2.049272E+00 1.059395E+02 1.942700E+04 2.017508E+00 1.060310E+02 1.949800E+04 2.011309E+00 1.061339E+02 1.961400E+04 2.032811E+00 1.062368E+02 1.933500E+04 2.014187E+00 1.063398E+02 1.912400E+04 1.990188E+00 1.064312E+02 1.951600E+04 2.062103E+00 1.065342E+02 1.903700E+04 2.030622E+00 1.066371E+02 1.910900E+04 2.058745E+00 1.067400E+02 1.887400E+04 1.979725E+00 1.068315E+02 1.874400E+04 1.937622E+00 1.069344E+02 1.878900E+04 1.952328E+00 1.070373E+02 1.866000E+04 1.987737E+00 1.071288E+02 1.868900E+04 1.984152E+00 1.072317E+02 1.869900E+04 2.044471E+00 1.073347E+02 1.881000E+04 2.048204E+00 1.074376E+02 1.857700E+04 2.013573E+00 1.075291E+02 1.831500E+04 2.048521E+00 1.076320E+02 1.861400E+04 2.098897E+00 1.077349E+02 1.860500E+04 2.040362E+00 1.078378E+02 1.838400E+04 2.090083E+00 1.079293E+02 1.838500E+04 2.188416E+00 1.080322E+02 1.837000E+04 2.254116E+00 1.081352E+02 1.846800E+04 2.217260E+00 1.082381E+02 1.842200E+04 2.229131E+00 1.083296E+02 1.841300E+04 2.260525E+00 1.084325E+02 1.853000E+04 2.372528E+00 1.086319E+02 1.813500E+04 2.370106E+00 1.088377E+02 1.835100E+04 2.418127E+00 1.090321E+02 1.829300E+04 2.500229E+00 1.092380E+02 1.806900E+04 2.520655E+00 1.094324E+02 1.821600E+04 2.525632E+00 1.096382E+02 1.817500E+04 2.655373E+00 1.098326E+02 1.809000E+04 2.718877E+00 1.100385E+02 1.787900E+04 2.665192E+00 1.102329E+02 1.784300E+04 2.766288E+00 1.104387E+02 1.752200E+04 2.757192E+00 1.106331E+02 1.769400E+04 2.813237E+00 1.108390E+02 1.754100E+04 2.778048E+00 1.110334E+02 1.754900E+04 2.788441E+00 1.112392E+02 1.705900E+04 2.832502E+00 1.114336E+02 1.703700E+04 2.918648E+00 1.116395E+02 1.723600E+04 2.940269E+00 1.118339E+02 1.722000E+04 2.937868E+00 1.120397E+02 1.704200E+04 2.966947E+00 1.122341E+02 1.709600E+04 3.026838E+00 1.124400E+02 1.691100E+04 3.002689E+00 1.126344E+02 1.678400E+04 3.015619E+00 1.128288E+02 1.670700E+04 3.070386E+00 1.130346E+02 1.661600E+04 3.021934E+00 1.132290E+02 1.659900E+04 3.036960E+00 1.134349E+02 1.637800E+04 3.072062E+00 1.136293E+02 1.635900E+04 3.118476E+00 1.138351E+02 1.620000E+04 3.071745E+00 1.140295E+02 1.602900E+04 2.977782E+00 1.142354E+02 1.589600E+04 2.986724E+00 1.144298E+02 1.612000E+04 3.056686E+00 1.146356E+02 1.575900E+04 2.975979E+00 1.148300E+02 1.563700E+04 2.973648E+00 1.150359E+02 1.555200E+04 3.011297E+00 1.152303E+02 1.575800E+04 3.067960E+00 1.154361E+02 1.550700E+04 3.074574E+00 1.156305E+02 1.528100E+04 3.076256E+00 1.158364E+02 1.528300E+04 3.037385E+00 1.160308E+02 1.526500E+04 3.095868E+00 1.162366E+02 1.516600E+04 3.067590E+00 1.164310E+02 1.502300E+04 3.033093E+00 1.166369E+02 1.486300E+04 3.144577E+00 1.168313E+02 1.509600E+04 3.197776E+00 1.170371E+02 1.489200E+04 3.154887E+00 1.172315E+02 1.486900E+04 3.233106E+00 1.174374E+02 1.487200E+04 3.210267E+00 1.176318E+02 1.493400E+04 3.295727E+00 1.178376E+02 1.456800E+04 3.223597E+00 1.180320E+02 1.496300E+04 3.340524E+00 1.182379E+02 1.489400E+04 3.347157E+00 1.184323E+02 1.459500E+04 3.356637E+00 1.186381E+02 1.457200E+04 3.420393E+00 1.188325E+02 1.447600E+04 3.419714E+00 1.190384E+02 1.469900E+04 3.510004E+00 1.192328E+02 1.442700E+04 3.486992E+00 1.194386E+02 1.431800E+04 3.487122E+00 1.196330E+02 1.427300E+04 3.550181E+00 1.198389E+02 1.423500E+04 3.589943E+00 1.200333E+02 1.411400E+04 3.666324E+00 1.202391E+02 1.415800E+04 3.647112E+00 1.204335E+02 1.431200E+04 3.704820E+00 1.207821E+02 1.427800E+04 3.777524E+00 1.211366E+02 1.420400E+04 3.842564E+00 1.214797E+02 1.405200E+04 3.808333E+00 1.218342E+02 1.397700E+04 3.869629E+00 1.221887E+02 1.422900E+04 4.030622E+00 1.225318E+02 1.383300E+04 3.996346E+00 1.228863E+02 1.398000E+04 4.096434E+00 1.232294E+02 1.372200E+04 4.169192E+00 1.235839E+02 1.384700E+04 4.211985E+00 1.239384E+02 1.366600E+04 4.262815E+00 1.242814E+02 1.362800E+04 4.293684E+00 1.246360E+02 1.356900E+04 4.391995E+00 1.249790E+02 1.356600E+04 4.408666E+00 1.253335E+02 1.361100E+04 4.512266E+00 1.256880E+02 1.345000E+04 4.527925E+00 1.260311E+02 1.344800E+04 4.567735E+00 1.263856E+02 1.320800E+04 4.588643E+00 1.267287E+02 1.315700E+04 4.597207E+00 1.270832E+02 1.306600E+04 4.619692E+00 1.274377E+02 1.308000E+04 4.676628E+00 1.277808E+02 1.273500E+04 4.631239E+00 1.281353E+02 1.287600E+04 4.666768E+00 1.284898E+02 1.298700E+04 4.708493E+00 1.288329E+02 1.234100E+04 4.610065E+00 1.291874E+02 1.230300E+04 4.637444E+00 1.295304E+02 1.242300E+04 4.685651E+00 1.298849E+02 1.232600E+04 4.607831E+00 1.302395E+02 1.226300E+04 4.635206E+00 1.305825E+02 1.200100E+04 4.581126E+00 1.309370E+02 1.176500E+04 4.525379E+00 1.312801E+02 1.166600E+04 4.595406E+00 1.316346E+02 1.167500E+04 4.635777E+00 1.319891E+02 1.129000E+04 4.533989E+00 1.323322E+02 1.137500E+04 4.524039E+00 1.326867E+02 1.139400E+04 4.524235E+00 1.330298E+02 1.111600E+04 4.481882E+00 1.333843E+02 1.116800E+04 4.506899E+00 1.337388E+02 1.081400E+04 4.423427E+00 1.340818E+02 1.086200E+04 4.446278E+00 1.344364E+02 1.093500E+04 4.431178E+00 1.347794E+02 1.063300E+04 4.348056E+00 1.351339E+02 1.052600E+04 4.405079E+00 1.354884E+02 1.041100E+04 4.359052E+00 1.358315E+02 1.032200E+04 4.357427E+00 1.361860E+02 1.037500E+04 4.393069E+00 1.365291E+02 1.017400E+04 4.356115E+00 1.368836E+02 1.012300E+04 4.362566E+00 1.372381E+02 9.961000E+03 4.300762E+00 1.375812E+02 9.956000E+03 4.309654E+00 1.379357E+02 9.997000E+03 4.343003E+00 1.382787E+02 9.688000E+03 4.292581E+00 1.386333E+02 9.750000E+03 4.337266E+00 1.389878E+02 9.511000E+03 4.281744E+00 1.393308E+02 9.449000E+03 4.268154E+00 1.396853E+02 9.433000E+03 4.284499E+00 1.400398E+02 9.339000E+03 4.286222E+00 1.403829E+02 9.268000E+03 4.278333E+00 1.407374E+02 9.349000E+03 4.259604E+00 1.410805E+02 9.052000E+03 4.220582E+00 1.414350E+02 9.028000E+03 4.250462E+00 1.417895E+02 9.027000E+03 4.245436E+00 1.421326E+02 8.991000E+03 4.272144E+00 1.424871E+02 8.845000E+03 4.332329E+00 1.428302E+02 8.958000E+03 4.350717E+00 1.431847E+02 8.749000E+03 4.266501E+00 1.435392E+02 8.713000E+03 4.199031E+00 1.438822E+02 8.745000E+03 4.211666E+00 1.442367E+02 8.431000E+03 4.235519E+00 1.445798E+02 8.290000E+03 4.202654E+00 1.449343E+02 8.466000E+03 4.256577E+00 1.452888E+02 8.303000E+03 4.199301E+00 1.456319E+02 8.298000E+03 4.216370E+00 1.459864E+02 8.161000E+03 4.221201E+00 1.463295E+02 8.321000E+03 4.270005E+00 1.466840E+02 7.897000E+03 4.190262E+00 1.470385E+02 8.131000E+03 4.222320E+00 1.473816E+02 8.069000E+03 4.200844E+00 1.477361E+02 7.911000E+03 4.161560E+00 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