********************* Core Excitation Data ******************** **************** A.P. Hitchcock & D.C. Mancini **************** * * Formula: Si(NtBuCH2CH2NtBu) * Name: saturated silylene * Edge: N 1s * Alpha Formula: C10H22N2Si * Data Source: Hitchcock * Filename: ut-0nnkk.os * Ref. Code: UH+98 * Write Date: 08/05/98 * Reference: Organometallics 17 (1998) 2352. * Source and Purity: Denk, sublimed under argon * Acquisition Mode: EELS, 2 deg, 2500eV CRE mode, 0.7eV fwhm *-------------------------------------------------------------- * No. of Spectra: 2 name1- 0utn4 name2- 0utn.os * E (eV) Raw data Osc. Str. per atom (E-2) *-------------------------------------------------------------- 3.904562E+02 3.308345E+03 -7.112564E-02 3.906506E+02 3.426662E+03 -9.419110E-03 3.908564E+02 3.386837E+03 1.678706E-02 3.910508E+02 3.362459E+03 1.831537E-02 3.912567E+02 3.430352E+03 1.594795E-02 3.914511E+02 3.411560E+03 3.051445E-02 3.916570E+02 3.323437E+03 4.290853E-02 3.918513E+02 3.316308E+03 3.245348E-02 3.920572E+02 3.403450E+03 2.388323E-02 3.922516E+02 3.297615E+03 -3.901524E-03 3.924575E+02 3.302110E+03 -5.137549E-02 3.926519E+02 3.254517E+03 3.120670E-02 3.928577E+02 3.291775E+03 -9.589734E-03 3.930521E+02 3.347846E+03 4.831674E-02 3.932579E+02 3.282744E+03 -1.291875E-04 3.934524E+02 3.141170E+03 -2.140186E-02 3.936582E+02 3.239831E+03 -4.041497E-02 3.938526E+02 3.223137E+03 2.482320E-02 3.940584E+02 3.211519E+03 3.190078E-04 3.942528E+02 3.258504E+03 -1.555186E-02 3.944587E+02 3.261953E+03 2.219557E-02 3.946531E+02 3.182141E+03 -6.895870E-02 3.948589E+02 3.236125E+03 3.203149E-02 3.950533E+02 3.223796E+03 -1.769838E-02 3.952478E+02 3.228388E+03 -2.078060E-02 3.954536E+02 3.239458E+03 3.539860E-03 3.956480E+02 3.082923E+03 -4.899832E-02 3.958539E+02 3.161972E+03 2.292956E-02 3.960482E+02 3.088030E+03 -1.066818E-01 3.962541E+02 3.088506E+03 4.593164E-03 3.964485E+02 3.180539E+03 3.394249E-02 3.966544E+02 3.106401E+03 -3.031671E-02 3.968488E+02 3.085839E+03 -4.101429E-02 3.970546E+02 3.102061E+03 6.403831E-02 3.972490E+02 3.103897E+03 1.531116E-02 3.974548E+02 3.099250E+03 -7.190930E-03 3.976493E+02 3.055000E+03 -2.668910E-02 3.978551E+02 3.097535E+03 -8.256422E-03 3.980495E+02 3.127825E+03 5.735773E-02 3.982553E+02 3.002738E+03 -2.314711E-02 3.983518E+02 2.993424E+03 7.672945E-03 3.984547E+02 3.207441E+03 7.478341E-02 3.985577E+02 3.131651E+03 4.125438E-02 3.986492E+02 3.143571E+03 1.407190E-01 3.987521E+02 3.070549E+03 8.035920E-02 3.988550E+02 3.151107E+03 2.614529E-01 3.989579E+02 3.246148E+03 3.767616E-01 3.990494E+02 3.307159E+03 4.673577E-01 3.991523E+02 3.413331E+03 5.959106E-01 3.992552E+02 3.566746E+03 8.057580E-01 3.993582E+02 3.544186E+03 8.617042E-01 3.994496E+02 3.621356E+03 9.758925E-01 3.995526E+02 3.684416E+03 1.090090E+00 3.996555E+02 3.693724E+03 1.063569E+00 3.997584E+02 3.601787E+03 9.640673E-01 3.998499E+02 3.613192E+03 8.879718E-01 3.999528E+02 3.563706E+03 7.952871E-01 4.000558E+02 3.389510E+03 6.524980E-01 4.001587E+02 3.321634E+03 5.024736E-01 4.002502E+02 3.222061E+03 3.810553E-01 4.003531E+02 3.186902E+03 3.157955E-01 4.004560E+02 3.013363E+03 2.212208E-01 4.005589E+02 3.054883E+03 2.144827E-01 4.006504E+02 3.055867E+03 2.714945E-01 4.007533E+02 3.037621E+03 1.870123E-01 4.008563E+02 3.269455E+03 3.502785E-01 4.009477E+02 3.088299E+03 2.959527E-01 4.010507E+02 3.219523E+03 3.735393E-01 4.011536E+02 3.203035E+03 4.482410E-01 4.012565E+02 3.231346E+03 4.536895E-01 4.013480E+02 3.306258E+03 5.130697E-01 4.014509E+02 3.318138E+03 5.554152E-01 4.015538E+02 3.294751E+03 5.959191E-01 4.016567E+02 3.266887E+03 6.120365E-01 4.017482E+02 3.385324E+03 7.034924E-01 4.018512E+02 3.349380E+03 6.608005E-01 4.019541E+02 3.361552E+03 6.768999E-01 4.020570E+02 3.376207E+03 7.374358E-01 4.021485E+02 3.448971E+03 7.580531E-01 4.022514E+02 3.337858E+03 7.299728E-01 4.023543E+02 3.442893E+03 8.411687E-01 4.024572E+02 3.425968E+03 9.406328E-01 4.025487E+02 3.510297E+03 9.294486E-01 4.026516E+02 3.463271E+03 1.025335E+00 4.027546E+02 3.630593E+03 1.156855E+00 4.028575E+02 3.523650E+03 1.131184E+00 4.029490E+02 3.594939E+03 1.144181E+00 4.030519E+02 3.627518E+03 1.173463E+00 4.031548E+02 3.623105E+03 1.213017E+00 4.032578E+02 3.511635E+03 1.152460E+00 4.033492E+02 3.715101E+03 1.236079E+00 4.034521E+02 3.628585E+03 1.235820E+00 4.035551E+02 3.767489E+03 1.300872E+00 4.036580E+02 3.681827E+03 1.288121E+00 4.037495E+02 3.608237E+03 1.247541E+00 4.038524E+02 3.683319E+03 1.353112E+00 4.039553E+02 3.602202E+03 1.275423E+00 4.040583E+02 3.599929E+03 1.325231E+00 4.041497E+02 3.579201E+03 1.259435E+00 4.042527E+02 3.528456E+03 1.260992E+00 4.043556E+02 3.607180E+03 1.234343E+00 4.044585E+02 3.605483E+03 1.242246E+00 4.045500E+02 3.588642E+03 1.266608E+00 4.046529E+02 3.561870E+03 1.212291E+00 4.047558E+02 3.570916E+03 1.191763E+00 4.048587E+02 3.639310E+03 1.218320E+00 4.049502E+02 3.577352E+03 1.169038E+00 4.050532E+02 3.618304E+03 1.274886E+00 4.051561E+02 3.585621E+03 1.294733E+00 4.052590E+02 3.619519E+03 1.220788E+00 4.053505E+02 3.750200E+03 1.300722E+00 4.054534E+02 3.666100E+03 1.222829E+00 4.055563E+02 3.583539E+03 1.308274E+00 4.056478E+02 3.655785E+03 1.253512E+00 4.057507E+02 3.606419E+03 1.236115E+00 4.058536E+02 3.481465E+03 1.269161E+00 4.059566E+02 3.559555E+03 1.240410E+00 4.060481E+02 3.509098E+03 1.290429E+00 4.061510E+02 3.576313E+03 1.241586E+00 4.062539E+02 3.566585E+03 1.192642E+00 4.063568E+02 3.590587E+03 1.276423E+00 4.064483E+02 3.597535E+03 1.295592E+00 4.065512E+02 3.569576E+03 1.254541E+00 4.066541E+02 3.521078E+03 1.234716E+00 4.067571E+02 3.552794E+03 1.248279E+00 4.068485E+02 3.568283E+03 1.290687E+00 4.069515E+02 3.590690E+03 1.255451E+00 4.070544E+02 3.620725E+03 1.278757E+00 4.071573E+02 3.612935E+03 1.271787E+00 4.072488E+02 3.508768E+03 1.282852E+00 4.073517E+02 3.490862E+03 1.204404E+00 4.074547E+02 3.459960E+03 1.248679E+00 4.075576E+02 3.523083E+03 1.230279E+00 4.076490E+02 3.430242E+03 1.201762E+00 4.077520E+02 3.458416E+03 1.205624E+00 4.078549E+02 3.463415E+03 1.221954E+00 4.079578E+02 3.447483E+03 1.185737E+00 4.080493E+02 3.453446E+03 1.257632E+00 4.081522E+02 3.461895E+03 1.232457E+00 4.082552E+02 3.433695E+03 1.178268E+00 4.083581E+02 3.495359E+03 1.201972E+00 4.084496E+02 3.474751E+03 1.184154E+00 4.085525E+02 3.366446E+03 1.197587E+00 4.086554E+02 3.315518E+03 1.117820E+00 4.087583E+02 3.509770E+03 1.143262E+00 4.088498E+02 3.509913E+03 1.225376E+00 4.089527E+02 3.540207E+03 1.268622E+00 4.090556E+02 3.442640E+03 1.173033E+00 4.091586E+02 3.506175E+03 1.212323E+00 4.092501E+02 3.433694E+03 1.194993E+00 4.093530E+02 3.386104E+03 1.200646E+00 4.094559E+02 3.413760E+03 1.176206E+00 4.095588E+02 3.396585E+03 1.162355E+00 4.096503E+02 3.436090E+03 1.155301E+00 4.097532E+02 3.383707E+03 1.127097E+00 4.098561E+02 3.394669E+03 1.134969E+00 4.099591E+02 3.399724E+03 1.113414E+00 4.100505E+02 3.359493E+03 1.130123E+00 4.101535E+02 3.449417E+03 1.121262E+00 4.102564E+02 3.448620E+03 1.132017E+00 4.104564E+02 3.314096E+03 1.065797E+00 4.106508E+02 3.315122E+03 1.066658E+00 4.108566E+02 3.324379E+03 1.028486E+00 4.110510E+02 3.268453E+03 1.045643E+00 4.112568E+02 3.247249E+03 1.065802E+00 4.114513E+02 3.260830E+03 1.005074E+00 4.116571E+02 3.304828E+03 1.030354E+00 4.118515E+02 3.371036E+03 1.061287E+00 4.120573E+02 3.319231E+03 1.021590E+00 4.122517E+02 3.138033E+03 1.034832E+00 4.124576E+02 3.198484E+03 9.526914E-01 4.126520E+02 3.175263E+03 9.917112E-01 4.128578E+02 3.224177E+03 9.933778E-01 4.130522E+02 3.180755E+03 9.893146E-01 4.132581E+02 3.163967E+03 9.181094E-01 4.134525E+02 3.195445E+03 9.493600E-01 4.136584E+02 3.034156E+03 9.184857E-01 4.138528E+02 3.078547E+03 9.300224E-01 4.140586E+02 3.067175E+03 9.083027E-01 4.142530E+02 3.072488E+03 8.620398E-01 4.144588E+02 3.166049E+03 9.120547E-01 4.146533E+02 3.216562E+03 8.960816E-01 4.148591E+02 3.143655E+03 9.152634E-01 4.150535E+02 3.088869E+03 8.653196E-01 4.152479E+02 2.969125E+03 7.995695E-01 4.154537E+02 3.031659E+03 8.264962E-01 4.156482E+02 3.133393E+03 8.855956E-01 4.158540E+02 3.096310E+03 9.081290E-01 4.160484E+02 3.027183E+03 8.226203E-01 4.162542E+02 3.046197E+03 8.162925E-01 4.164487E+02 2.956227E+03 8.220676E-01 4.166545E+02 2.905241E+03 8.477893E-01 4.168489E+02 2.964109E+03 8.732210E-01 4.170547E+02 2.975513E+03 7.811493E-01 4.172491E+02 2.934306E+03 7.866657E-01 4.174550E+02 2.890971E+03 8.122939E-01 4.176494E+02 2.888927E+03 7.665691E-01 4.178553E+02 2.924375E+03 7.920342E-01 4.180497E+02 2.964080E+03 7.978855E-01 4.182555E+02 2.928833E+03 7.170559E-01 4.184499E+02 2.874097E+03 7.098750E-01 4.186557E+02 2.825337E+03 7.531754E-01 4.188502E+02 2.946197E+03 7.509225E-01 4.190560E+02 2.910379E+03 6.838233E-01 4.192504E+02 2.899584E+03 7.189732E-01 4.194562E+02 2.778948E+03 6.744359E-01 4.196507E+02 2.856211E+03 7.218319E-01 4.198565E+02 2.755929E+03 7.032053E-01 4.200509E+02 2.818452E+03 6.704447E-01 4.202567E+02 2.801665E+03 6.360982E-01 4.204511E+02 2.813898E+03 6.820716E-01 4.206570E+02 2.854104E+03 5.931995E-01 4.208514E+02 2.760592E+03 6.089109E-01 4.210573E+02 2.841453E+03 7.268586E-01 4.212516E+02 2.802608E+03 6.146370E-01 4.214575E+02 2.821342E+03 6.983258E-01 4.216519E+02 2.685827E+03 6.269222E-01 4.218577E+02 2.755069E+03 6.129856E-01 4.220522E+02 2.673872E+03 6.003011E-01 4.222580E+02 2.688414E+03 6.031137E-01 4.224524E+02 2.694634E+03 5.870726E-01 4.226582E+02 2.632648E+03 6.172134E-01 4.228527E+02 2.594633E+03 5.828425E-01 4.230585E+02 2.743760E+03 6.249818E-01 4.232529E+02 2.678059E+03 5.879329E-01 4.234587E+02 2.654318E+03 5.866447E-01 4.236531E+02 2.642808E+03 5.566741E-01 4.238590E+02 2.709967E+03 6.330773E-01 4.240534E+02 2.682555E+03 6.377990E-01 4.242478E+02 2.668876E+03 5.898908E-01 4.244536E+02 2.558185E+03 5.595748E-01 4.246480E+02 2.619490E+03 5.690198E-01 4.248539E+02 2.715312E+03 5.792664E-01 4.250483E+02 2.563483E+03 5.824285E-01 4.252542E+02 2.534240E+03 5.638525E-01 4.256530E+02 2.628477E+03 5.950891E-01 4.260533E+02 2.518183E+03 4.824020E-01 4.264421E+02 2.593970E+03 5.889268E-01 4.268423E+02 2.556492E+03 5.655860E-01 4.272311E+02 2.557807E+03 5.522848E-01 4.276314E+02 2.505583E+03 5.567147E-01 4.280202E+02 2.483322E+03 5.033361E-01 4.284204E+02 2.533469E+03 5.026010E-01 4.288093E+02 2.562410E+03 5.020626E-01 4.292095E+02 2.535115E+03 5.393691E-01 4.295983E+02 2.463140E+03 5.872005E-01 4.299986E+02 2.485941E+03 5.519755E-01 4.303874E+02 2.525182E+03 5.974511E-01 4.307876E+02 2.450067E+03 6.123552E-01 4.311765E+02 2.508793E+03 6.386762E-01 4.315767E+02 2.508050E+03 5.917364E-01 4.319655E+02 2.435815E+03 5.314972E-01 4.323658E+02 2.430394E+03 5.055445E-01 4.327546E+02 2.304303E+03 4.046085E-01 4.331548E+02 2.403624E+03 5.855753E-01 4.335436E+02 2.403998E+03 5.107513E-01 4.339439E+02 2.405251E+03 5.586522E-01 4.343327E+02 2.429680E+03 5.753552E-01 4.347330E+02 2.415293E+03 5.405089E-01 4.351218E+02 2.292867E+03 4.873154E-01 4.355220E+02 2.397235E+03 5.208051E-01 4.359108E+02 2.347059E+03 5.399041E-01 4.363111E+02 2.383583E+03 5.259318E-01 4.366999E+02 2.326005E+03 5.388246E-01 4.371002E+02 2.303917E+03 5.043355E-01 4.374890E+02 2.274446E+03 4.933384E-01 4.378892E+02 2.282862E+03 4.974285E-01 4.382780E+02 2.327131E+03 5.641594E-01 4.386783E+02 2.274550E+03 5.544423E-01 4.390671E+02 2.201415E+03 4.930447E-01 4.394673E+02 2.219406E+03 4.567494E-01 4.398561E+02 2.247345E+03 4.982244E-01 4.402564E+02 2.278990E+03 4.888921E-01