********************* Core Excitation Data ******************** **************** A.P. Hitchcock & D.C. Mancini **************** * * Formula: Si(NtBuCH2CH2NtBu) * Name: saturated silylene * Edge: C 1s * Alpha Formula: C10H22N2Si * Data Source: Hitchcock * Filename: ut-0cckk.os * Ref. Code: UH+98 * Write Date: 08/05/98 * Reference: Organometallics 17 (1998) 2352. * Source and Purity: Denk, sublimed under argon * Acquisition Mode: EELS, 2 deg, 2500eV CRE mode, 0.7eV fwhm *-------------------------------------------------------------- * No. of Spectra: 2 name1- 0utc6 name2- 0utc.os * E (eV) Raw data Osc. Str. per atom (E-2) *-------------------------------------------------------------- 2.707856E+02 1.514470E+03 -7.916725E-03 2.709801E+02 1.548611E+03 -2.339517E-03 2.711860E+02 1.561540E+03 1.886723E-03 2.713805E+02 1.527053E+03 1.498942E-03 2.715864E+02 1.578465E+03 7.546318E-03 2.717809E+02 1.452176E+03 -1.200194E-02 2.719868E+02 1.577165E+03 1.064259E-02 2.721812E+02 1.542456E+03 5.583005E-03 2.723871E+02 1.481508E+03 -6.436714E-03 2.725816E+02 1.514177E+03 -2.109820E-03 2.727875E+02 1.498151E+03 -5.799569E-03 2.729820E+02 1.518654E+03 2.473420E-03 2.731879E+02 1.511977E+03 1.858495E-03 2.733824E+02 1.454385E+03 -4.051314E-03 2.735883E+02 1.518154E+03 4.854009E-03 2.737827E+02 1.491619E+03 5.802486E-03 2.739886E+02 1.462915E+03 1.029887E-03 2.741831E+02 1.425420E+03 -9.657130E-03 2.743890E+02 1.453147E+03 -3.669116E-03 2.745835E+02 1.467346E+03 -6.555877E-03 2.747780E+02 1.538426E+03 1.160859E-02 2.749839E+02 1.434286E+03 -1.890262E-03 2.751783E+02 1.445375E+03 -2.912870E-03 2.753842E+02 1.483795E+03 4.453471E-03 2.755787E+02 1.511065E+03 9.303824E-03 2.757846E+02 1.443783E+03 -5.077384E-03 2.759791E+02 1.432680E+03 3.601135E-03 2.761850E+02 1.441243E+03 2.663306E-05 2.763795E+02 1.401175E+03 -6.234220E-03 2.765854E+02 1.400119E+03 -5.512837E-03 2.767798E+02 1.479120E+03 7.513403E-03 2.769857E+02 1.427411E+03 2.754109E-03 2.771802E+02 1.382362E+03 -4.767979E-03 2.773861E+02 1.434231E+03 1.568867E-03 2.775806E+02 1.390300E+03 -1.766352E-03 2.777865E+02 1.450483E+03 6.079383E-03 2.779810E+02 1.409771E+03 -1.986543E-03 2.781869E+02 1.401624E+03 1.849281E-03 2.783813E+02 1.415367E+03 2.573849E-03 2.785872E+02 1.450920E+03 1.191466E-02 2.787817E+02 1.415440E+03 6.698591E-03 2.789876E+02 1.392713E+03 4.429440E-03 2.791821E+02 1.441086E+03 1.600253E-02 2.793880E+02 1.362739E+03 -1.426594E-03 2.795825E+02 1.344439E+03 -3.349130E-03 2.797884E+02 1.399377E+03 -3.219526E-03 2.799828E+02 1.403385E+03 5.233615E-03 2.801888E+02 1.372596E+03 -2.283340E-03 2.803832E+02 1.321382E+03 -9.033878E-03 2.805891E+02 1.375540E+03 -5.523436E-03 2.807836E+02 1.388236E+03 1.611889E-04 2.809781E+02 1.354823E+03 -2.765800E-03 2.811840E+02 1.302160E+03 -1.037514E-02 2.813784E+02 1.338769E+03 1.298706E-03 2.815844E+02 1.347034E+03 6.842936E-04 2.817788E+02 1.278926E+03 -9.241767E-03 2.819847E+02 1.292962E+03 -8.342125E-03 2.821792E+02 1.303185E+03 -8.215606E-03 2.823851E+02 1.334081E+03 4.028743E-03 2.825796E+02 1.351509E+03 2.569982E-03 2.827855E+02 1.340341E+03 3.007212E-03 2.829799E+02 1.329797E+03 -4.569910E-03 2.831859E+02 1.318622E+03 -4.010213E-03 2.833803E+02 1.308078E+03 -8.840440E-04 2.835862E+02 1.296910E+03 -4.615808E-03 2.837807E+02 1.282640E+03 -5.113677E-03 2.838839E+02 1.266971E+03 -7.800522E-03 2.839868E+02 1.300387E+03 -1.035963E-04 2.840783E+02 1.295265E+03 2.378136E-03 2.841813E+02 1.288935E+03 -1.133885E-03 2.842842E+02 1.304800E+03 -6.604982E-03 2.843872E+02 1.295909E+03 -1.462457E-03 2.844787E+02 1.351000E+03 9.595925E-03 2.845817E+02 1.338192E+03 1.030749E-02 2.846846E+02 1.281772E+03 -1.941255E-03 2.847876E+02 1.273232E+03 1.226605E-03 2.848791E+02 1.320503E+03 7.552070E-03 2.849821E+02 1.322531E+03 1.118165E-02 2.850850E+02 1.313158E+03 6.995318E-03 2.851880E+02 1.369785E+03 2.175707E-02 2.852795E+02 1.360256E+03 2.163174E-02 2.853824E+02 1.349523E+03 1.471457E-02 2.854854E+02 1.375952E+03 2.115733E-02 2.855883E+02 1.409572E+03 2.672684E-02 2.856798E+02 1.369363E+03 1.330963E-02 2.857828E+02 1.423109E+03 2.779806E-02 2.858857E+02 1.493062E+03 4.716998E-02 2.859887E+02 1.551530E+03 6.025935E-02 2.860802E+02 1.657668E+03 8.348103E-02 2.861832E+02 1.946065E+03 1.320166E-01 2.862861E+02 2.157251E+03 1.732277E-01 2.863891E+02 2.426194E+03 2.383962E-01 2.864806E+02 2.696409E+03 2.950209E-01 2.865836E+02 3.176861E+03 3.952589E-01 2.866865E+02 3.639468E+03 5.043305E-01 2.867780E+02 4.006368E+03 5.903370E-01 2.868810E+02 4.313246E+03 6.809424E-01 2.869839E+02 4.755937E+03 7.946671E-01 2.870869E+02 5.122093E+03 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7.944396E+03 1.560096E+00 2.897866E+02 8.066710E+03 1.580119E+00 2.898781E+02 8.223104E+03 1.617943E+00 2.899810E+02 8.308588E+03 1.641999E+00 2.900840E+02 8.346596E+03 1.648657E+00 2.901869E+02 8.393423E+03 1.674552E+00 2.902784E+02 8.641754E+03 1.733658E+00 2.903814E+02 8.704868E+03 1.754700E+00 2.904843E+02 8.710012E+03 1.751925E+00 2.905873E+02 8.702283E+03 1.762176E+00 2.906788E+02 8.974543E+03 1.818331E+00 2.907818E+02 8.932852E+03 1.807765E+00 2.908847E+02 9.045827E+03 1.821547E+00 2.909877E+02 9.016156E+03 1.824453E+00 2.910792E+02 9.016692E+03 1.846818E+00 2.911822E+02 9.042463E+03 1.865274E+00 2.912851E+02 9.132119E+03 1.863008E+00 2.913881E+02 9.240267E+03 1.885375E+00 2.914796E+02 9.182743E+03 1.883550E+00 2.915825E+02 9.205414E+03 1.905139E+00 2.916855E+02 9.189458E+03 1.890711E+00 2.917884E+02 9.191397E+03 1.900424E+00 2.918799E+02 9.223448E+03 1.896721E+00 2.919829E+02 9.247744E+03 1.914556E+00 2.920858E+02 9.233972E+03 1.910300E+00 2.921888E+02 9.214495E+03 1.901310E+00 2.922803E+02 9.187807E+03 1.910208E+00 2.923833E+02 9.147370E+03 1.896657E+00 2.924862E+02 9.074250E+03 1.881139E+00 2.925892E+02 9.027532E+03 1.879344E+00 2.926807E+02 9.028867E+03 1.868661E+00 2.927837E+02 9.022185E+03 1.875100E+00 2.928866E+02 8.990393E+03 1.858543E+00 2.929781E+02 8.979668E+03 1.850100E+00 2.930811E+02 9.018743E+03 1.861708E+00 2.931840E+02 9.017190E+03 1.849482E+00 2.932870E+02 8.894136E+03 1.823913E+00 2.933785E+02 8.779429E+03 1.793668E+00 2.934814E+02 8.635364E+03 1.782013E+00 2.935844E+02 8.545747E+03 1.770130E+00 2.936873E+02 8.615148E+03 1.776965E+00 2.937789E+02 8.627566E+03 1.773969E+00 2.939826E+02 8.390413E+03 1.735859E+00 2.941885E+02 8.219829E+03 1.693644E+00 2.943830E+02 8.213399E+03 1.689049E+00 2.945889E+02 7.958821E+03 1.643963E+00 2.947834E+02 7.831480E+03 1.608346E+00 2.949893E+02 7.816863E+03 1.599340E+00 2.951837E+02 7.534414E+03 1.575183E+00 2.953782E+02 7.378310E+03 1.517346E+00 2.955841E+02 7.384409E+03 1.499789E+00 2.957786E+02 7.307530E+03 1.494427E+00 2.959845E+02 7.177768E+03 1.460439E+00 2.961790E+02 7.033960E+03 1.435599E+00 2.963849E+02 6.899886E+03 1.429691E+00 2.965793E+02 6.842245E+03 1.398839E+00 2.967852E+02 6.841891E+03 1.397211E+00 2.969797E+02 6.714790E+03 1.378369E+00 2.971856E+02 6.692165E+03 1.364475E+00 2.973801E+02 6.635801E+03 1.352808E+00 2.975860E+02 6.609696E+03 1.357197E+00 2.977805E+02 6.601690E+03 1.349434E+00 2.979864E+02 6.368863E+03 1.308473E+00 2.981808E+02 6.405396E+03 1.332862E+00 2.983867E+02 6.341071E+03 1.315241E+00 2.985812E+02 6.394818E+03 1.312175E+00 2.987871E+02 6.374601E+03 1.309996E+00 2.989816E+02 6.288365E+03 1.290924E+00 2.991875E+02 6.200487E+03 1.293999E+00 2.993820E+02 6.195396E+03 1.269880E+00 2.995879E+02 6.212987E+03 1.276202E+00 2.997823E+02 6.129048E+03 1.262862E+00 2.999883E+02 5.976940E+03 1.239887E+00 3.001827E+02 5.983615E+03 1.238477E+00 3.003886E+02 5.978121E+03 1.236664E+00 3.005831E+02 5.871917E+03 1.222496E+00 3.007890E+02 5.809794E+03 1.191622E+00 3.009835E+02 5.736695E+03 1.168050E+00 3.011779E+02 5.709472E+03 1.169460E+00 3.013839E+02 5.755346E+03 1.180308E+00 3.015783E+02 5.692805E+03 1.176057E+00 3.017842E+02 5.647553E+03 1.162839E+00 3.019787E+02 5.551058E+03 1.152941E+00 3.021846E+02 5.485209E+03 1.132308E+00 3.023791E+02 5.614759E+03 1.155719E+00 3.025850E+02 5.473859E+03 1.144809E+00 3.027794E+02 5.408882E+03 1.120845E+00 3.029854E+02 5.409262E+03 1.123087E+00 3.031798E+02 5.394435E+03 1.131239E+00 3.033857E+02 5.227409E+03 1.089636E+00 3.035802E+02 5.264613E+03 1.090154E+00 3.037861E+02 5.249125E+03 1.104806E+00 3.039806E+02 5.115000E+03 1.071598E+00 3.041865E+02 5.094842E+03 1.049237E+00 3.043809E+02 5.043289E+03 1.043573E+00 3.045869E+02 4.965458E+03 1.021768E+00 3.047813E+02 4.993853E+03 1.035823E+00 3.049872E+02 5.080000E+03 1.048200E+00 3.051817E+02 5.055136E+03 1.027969E+00 3.053876E+02 4.903604E+03 1.010131E+00 3.055821E+02 4.961345E+03 1.032982E+00 3.057880E+02 4.887633E+03 1.018375E+00 3.059824E+02 4.913472E+03 1.025997E+00 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