********************* Core Excitation Data ******************** **************** A.P. Hitchcock & D.C. Mancini **************** * * Formula: H2Si(NtBuCH2CH2NtBu) * Name: saturated SiH2 silylene * Edge: N 1s * Alpha Formula: C10H24N2Si * Data Source: Hitchcock * Filename: us-0nnkk.os * Ref. Code: UH+98 * Write Date: 08/05/98 * Reference: Organometallics 17 (1998) 2352. * Source and Purity: Denk, vacuum distilled * Acquisition Mode: EELS, 2 deg, 2500eV CRE mode, 0.7eV fwhm *-------------------------------------------------------------- * No. of Spectra: 2 name1- 0usn1 name2- 0usn.os * E (eV) Raw data Osc. Str. per atom (E-2) *-------------------------------------------------------------- 3.852645E+02 8.793000E+03 -2.463218E-02 3.854588E+02 8.840000E+03 5.223868E-03 3.856645E+02 8.848000E+03 -1.368305E-02 3.858588E+02 8.892000E+03 1.881034E-02 3.860645E+02 8.714000E+03 -1.071027E-02 3.862588E+02 8.666000E+03 -2.609533E-02 3.864645E+02 8.728000E+03 4.614573E-02 3.866588E+02 8.682000E+03 5.465422E-03 3.868645E+02 8.842000E+03 2.820084E-02 3.870588E+02 8.526000E+03 -5.441026E-02 3.872645E+02 8.439000E+03 -2.197255E-02 3.874588E+02 8.536000E+03 1.715710E-03 3.876645E+02 8.615000E+03 7.724758E-03 3.878588E+02 8.533000E+03 -2.831893E-02 3.880645E+02 8.649000E+03 3.073984E-02 3.882588E+02 8.540000E+03 -7.558995E-03 3.884645E+02 8.436000E+03 5.656550E-03 3.886588E+02 8.499000E+03 1.052657E-03 3.888645E+02 8.624000E+03 2.712133E-02 3.890588E+02 8.501000E+03 1.823762E-02 3.892645E+02 8.453000E+03 -5.826791E-02 3.894588E+02 8.451000E+03 1.192864E-02 3.896645E+02 8.350000E+03 1.368426E-02 3.898588E+02 8.386000E+03 2.578808E-02 3.900645E+02 8.393000E+03 2.077791E-02 3.902588E+02 8.489000E+03 3.067534E-02 3.904645E+02 8.244000E+03 -3.381708E-02 3.906588E+02 8.353000E+03 -3.411995E-02 3.908645E+02 8.349000E+03 1.091453E-02 3.910588E+02 8.439000E+03 3.580186E-02 3.912645E+02 8.409000E+03 6.788851E-02 3.914588E+02 8.156000E+03 -2.729728E-02 3.916645E+02 8.307000E+03 1.369765E-02 3.918588E+02 8.324000E+03 5.461909E-02 3.920645E+02 8.254000E+03 -4.071259E-03 3.922588E+02 8.032000E+03 -1.030672E-02 3.928645E+02 8.099000E+03 2.813975E-02 3.930588E+02 8.106000E+03 -5.764540E-03 3.932645E+02 8.070000E+03 -1.894714E-02 3.934588E+02 8.103000E+03 -5.941427E-03 3.936645E+02 7.961000E+03 -2.173257E-02 3.938588E+02 7.975000E+03 -3.484887E-03 3.940645E+02 8.083000E+03 1.114722E-02 3.942588E+02 8.096000E+03 1.638870E-02 3.944645E+02 7.976000E+03 -3.025032E-02 3.946588E+02 7.890000E+03 -5.134457E-02 3.948645E+02 7.706000E+03 -4.149208E-02 3.950588E+02 7.890000E+03 2.276653E-02 3.952645E+02 7.736000E+03 -3.945807E-02 3.954588E+02 7.874000E+03 -4.019635E-02 3.956645E+02 7.767000E+03 -5.673997E-02 3.958588E+02 8.037000E+03 1.382780E-02 3.960645E+02 7.825000E+03 -3.308704E-02 3.962588E+02 7.719000E+03 -2.188923E-02 3.964645E+02 7.868000E+03 1.343450E-02 3.966588E+02 7.764000E+03 -3.828828E-02 3.968645E+02 7.774000E+03 5.454165E-03 3.970588E+02 7.792000E+03 3.868006E-02 3.972645E+02 7.775000E+03 1.039200E-02 3.974588E+02 7.652000E+03 2.208863E-02 3.976645E+02 7.729000E+03 3.169565E-02 3.978588E+02 7.828000E+03 -1.229771E-02 3.980645E+02 7.756000E+03 1.457280E-02 3.981581E+02 7.593000E+03 -2.554948E-02 3.982610E+02 7.772000E+03 4.376847E-02 3.983638E+02 7.458000E+03 -3.302772E-02 3.984552E+02 7.615000E+03 5.670832E-02 3.985581E+02 7.499000E+03 -3.640547E-02 3.986609E+02 7.763000E+03 1.354078E-02 3.987638E+02 7.781000E+03 4.297304E-02 3.988552E+02 7.563000E+03 4.759387E-03 3.989581E+02 7.861000E+03 4.515485E-02 3.990609E+02 7.717000E+03 2.484629E-02 3.991638E+02 7.604000E+03 -1.790100E-02 3.992552E+02 7.716000E+03 1.772033E-02 3.993581E+02 7.597000E+03 4.459075E-02 3.994609E+02 7.611000E+03 5.843687E-02 3.995638E+02 7.471000E+03 -2.375595E-04 3.996552E+02 7.578000E+03 3.789072E-02 3.997581E+02 7.472000E+03 -2.068475E-02 3.998610E+02 7.514000E+03 -1.608713E-02 3.999638E+02 7.626000E+03 -6.297560E-03 4.000552E+02 7.678000E+03 4.337655E-02 4.001581E+02 7.529000E+03 2.491581E-02 4.002610E+02 7.598000E+03 6.787010E-02 4.003638E+02 7.758000E+03 1.242348E-01 4.004552E+02 7.815000E+03 1.766473E-01 4.005581E+02 8.053000E+03 2.798278E-01 4.006609E+02 8.161000E+03 3.857046E-01 4.007638E+02 8.217000E+03 4.209969E-01 4.008552E+02 8.265000E+03 5.130754E-01 4.009581E+02 8.542000E+03 6.585024E-01 4.010609E+02 8.638000E+03 7.516940E-01 4.011638E+02 8.781000E+03 7.368575E-01 4.012552E+02 8.688000E+03 7.639019E-01 4.013581E+02 8.569000E+03 7.379732E-01 4.014610E+02 8.818000E+03 7.768584E-01 4.015638E+02 8.661000E+03 7.570784E-01 4.016552E+02 8.543000E+03 7.081697E-01 4.017581E+02 8.604000E+03 7.415410E-01 4.018610E+02 8.361000E+03 6.929962E-01 4.019638E+02 8.628000E+03 7.981863E-01 4.020552E+02 8.659000E+03 7.446190E-01 4.021581E+02 8.769000E+03 7.726257E-01 4.022610E+02 8.761000E+03 8.459759E-01 4.023638E+02 8.836000E+03 9.039866E-01 4.024552E+02 9.000000E+03 9.555810E-01 4.025581E+02 9.252000E+03 1.090419E+00 4.026609E+02 9.075000E+03 1.103975E+00 4.027638E+02 9.457000E+03 1.276188E+00 4.028553E+02 9.473000E+03 1.325409E+00 4.029581E+02 9.389000E+03 1.328132E+00 4.030609E+02 9.549000E+03 1.380826E+00 4.031638E+02 9.458000E+03 1.372010E+00 4.032552E+02 9.551000E+03 1.432762E+00 4.033581E+02 9.859000E+03 1.515126E+00 4.034610E+02 9.818000E+03 1.571261E+00 4.035638E+02 9.739000E+03 1.512914E+00 4.036552E+02 9.768000E+03 1.521845E+00 4.037581E+02 9.831000E+03 1.539038E+00 4.038610E+02 9.796000E+03 1.540070E+00 4.039638E+02 9.625000E+03 1.554973E+00 4.040552E+02 9.842000E+03 1.560469E+00 4.041581E+02 9.741000E+03 1.557121E+00 4.042610E+02 9.748000E+03 1.575278E+00 4.043638E+02 9.845000E+03 1.549205E+00 4.044553E+02 9.549000E+03 1.502876E+00 4.045581E+02 9.765000E+03 1.590460E+00 4.046609E+02 9.564000E+03 1.542957E+00 4.047638E+02 9.652000E+03 1.539382E+00 4.048553E+02 9.779000E+03 1.564453E+00 4.049581E+02 9.623000E+03 1.530727E+00 4.050610E+02 9.670000E+03 1.580714E+00 4.051638E+02 9.629000E+03 1.560867E+00 4.052552E+02 9.736000E+03 1.580647E+00 4.053581E+02 9.502000E+03 1.575760E+00 4.054610E+02 9.572000E+03 1.555832E+00 4.055638E+02 9.683000E+03 1.586549E+00 4.056552E+02 9.630000E+03 1.571680E+00 4.057581E+02 9.879000E+03 1.612607E+00 4.058610E+02 9.552000E+03 1.543738E+00 4.059638E+02 9.630000E+03 1.519565E+00 4.060552E+02 9.493000E+03 1.533987E+00 4.061581E+02 9.561000E+03 1.525209E+00 4.062610E+02 9.416000E+03 1.523457E+00 4.064553E+02 9.415000E+03 1.471702E+00 4.065581E+02 9.383000E+03 1.463996E+00 4.066610E+02 9.410000E+03 1.483725E+00 4.067638E+02 9.365000E+03 1.475760E+00 4.068553E+02 9.411000E+03 1.483552E+00 4.069581E+02 9.258000E+03 1.462146E+00 4.070610E+02 9.332000E+03 1.440132E+00 4.071638E+02 9.122000E+03 1.429279E+00 4.072552E+02 9.224000E+03 1.455547E+00 4.073581E+02 9.216000E+03 1.374971E+00 4.074610E+02 9.098000E+03 1.356116E+00 4.075638E+02 9.149000E+03 1.364064E+00 4.076552E+02 9.174000E+03 1.416312E+00 4.077581E+02 9.251000E+03 1.413743E+00 4.078610E+02 9.184000E+03 1.430819E+00 4.079638E+02 8.832000E+03 1.339277E+00 4.080553E+02 9.006000E+03 1.354726E+00 4.081581E+02 9.103000E+03 1.363929E+00 4.082610E+02 9.098000E+03 1.339746E+00 4.083638E+02 8.856000E+03 1.293829E+00 4.084553E+02 8.981000E+03 1.333633E+00 4.085581E+02 8.882000E+03 1.320171E+00 4.086610E+02 8.994000E+03 1.355703E+00 4.087638E+02 8.979000E+03 1.364158E+00 4.088553E+02 8.861000E+03 1.290608E+00 4.089581E+02 8.958000E+03 1.322160E+00 4.090610E+02 8.869000E+03 1.319368E+00 4.091638E+02 8.895000E+03 1.303796E+00 4.092552E+02 8.922000E+03 1.310332E+00 4.093581E+02 8.747000E+03 1.282295E+00 4.094610E+02 8.748000E+03 1.271667E+00 4.095638E+02 8.878000E+03 1.232643E+00 4.096553E+02 8.770000E+03 1.217013E+00 4.097581E+02 8.714000E+03 1.247078E+00 4.098610E+02 8.600000E+03 1.199998E+00 4.099638E+02 8.686000E+03 1.187602E+00 4.100553E+02 8.575000E+03 1.189477E+00 4.101581E+02 8.624000E+03 1.200449E+00 4.102610E+02 8.640000E+03 1.194923E+00 4.103638E+02 8.637000E+03 1.180212E+00 4.104553E+02 8.531000E+03 1.146904E+00 4.105581E+02 8.469000E+03 1.141474E+00 4.106610E+02 8.452000E+03 1.138271E+00 4.107638E+02 8.354000E+03 1.111291E+00 4.108553E+02 8.502000E+03 1.127742E+00 4.109581E+02 8.387000E+03 1.098556E+00 4.110610E+02 8.356000E+03 1.093663E+00 4.111638E+02 8.328000E+03 1.100469E+00 4.112553E+02 8.299000E+03 1.082309E+00 4.113581E+02 8.246000E+03 1.044997E+00 4.114610E+02 8.459000E+03 1.064268E+00 4.115638E+02 8.333000E+03 1.036043E+00 4.116553E+02 8.284000E+03 1.034553E+00 4.117581E+02 8.051000E+03 9.866537E-01 4.118610E+02 8.180000E+03 9.938961E-01 4.119638E+02 8.293000E+03 1.023405E+00 4.120553E+02 8.282000E+03 1.026626E+00 4.122652E+02 8.118000E+03 9.890382E-01 4.124595E+02 8.092000E+03 1.049022E+00 4.126652E+02 8.236000E+03 1.022697E+00 4.128595E+02 8.035000E+03 9.940552E-01 4.130652E+02 8.216000E+03 1.041912E+00 4.132595E+02 7.922000E+03 9.344848E-01 4.134652E+02 8.071000E+03 1.032225E+00 4.136595E+02 7.957000E+03 1.006556E+00 4.138652E+02 7.997000E+03 9.673613E-01 4.140595E+02 7.991000E+03 9.623484E-01 4.142652E+02 7.968000E+03 9.668183E-01 4.144595E+02 7.807000E+03 9.137054E-01 4.146652E+02 7.898000E+03 9.029665E-01 4.148595E+02 7.909000E+03 9.652553E-01 4.150652E+02 7.782000E+03 9.633164E-01 4.152595E+02 7.814000E+03 9.104598E-01 4.154652E+02 7.693000E+03 8.808880E-01 4.156595E+02 7.602000E+03 8.804684E-01 4.158652E+02 7.690000E+03 8.945381E-01 4.160595E+02 7.625000E+03 8.419549E-01 4.162652E+02 7.605000E+03 8.158854E-01 4.164595E+02 7.638000E+03 8.294612E-01 4.166652E+02 7.826000E+03 8.968624E-01 4.168595E+02 7.510000E+03 8.288814E-01 4.170652E+02 7.530000E+03 8.484407E-01 4.172595E+02 7.522000E+03 8.191997E-01 4.174652E+02 7.248000E+03 7.469814E-01 4.176595E+02 7.622000E+03 8.425994E-01 4.178652E+02 7.283000E+03 7.141933E-01 4.180595E+02 7.444000E+03 8.075825E-01 4.182652E+02 7.222000E+03 7.592561E-01 4.184595E+02 7.214000E+03 7.060890E-01 4.186653E+02 7.297000E+03 7.456174E-01 4.188595E+02 7.429000E+03 7.641703E-01 4.190652E+02 7.321000E+03 7.616878E-01 4.192595E+02 7.032000E+03 7.015824E-01 4.194652E+02 7.288000E+03 7.502756E-01 4.196595E+02 7.267000E+03 7.431346E-01 4.198652E+02 7.168000E+03 6.471856E-01 4.200595E+02 7.171000E+03 7.022812E-01 4.202652E+02 7.080000E+03 6.932442E-01 4.204595E+02 7.108000E+03 6.941253E-01 4.206653E+02 7.229000E+03 7.047001E-01 4.208595E+02 7.161000E+03 6.943557E-01 4.210652E+02 6.999000E+03 6.673492E-01 4.212595E+02 6.895000E+03 6.474427E-01 4.214652E+02 7.059000E+03 6.519365E-01 4.216595E+02 6.991000E+03 6.311336E-01 4.218652E+02 6.882000E+03 6.150134E-01 4.220595E+02 6.914000E+03 6.350043E-01 4.222653E+02 6.837000E+03 6.338631E-01 4.224595E+02 6.908000E+03 6.562517E-01 4.226538E+02 6.674000E+03 5.935657E-01 4.228595E+02 6.886000E+03 6.186134E-01 4.230538E+02 6.794000E+03 5.911839E-01 4.232595E+02 6.779000E+03 6.114998E-01 4.236595E+02 6.889000E+03 6.620750E-01 4.238538E+02 6.841000E+03 6.712865E-01 4.240595E+02 6.816000E+03 6.649295E-01 4.242538E+02 6.760000E+03 6.237429E-01 4.244595E+02 6.816000E+03 6.671750E-01 4.246538E+02 6.754000E+03 6.547937E-01 4.248595E+02 6.824000E+03 6.484914E-01 4.250538E+02 6.629000E+03 5.959715E-01 4.254102E+02 6.616000E+03 6.042449E-01 4.257645E+02 6.796000E+03 6.079478E-01 4.261188E+02 6.626000E+03 5.826998E-01 4.264617E+02 6.505000E+03 5.795601E-01 4.268159E+02 6.688000E+03 6.222460E-01 4.271703E+02 6.456000E+03 5.767525E-01 4.275245E+02 6.352000E+03 5.654906E-01 4.278788E+02 6.410000E+03 5.817345E-01 4.282217E+02 6.456000E+03 5.755999E-01 4.285760E+02 6.431000E+03 5.351583E-01 4.289302E+02 6.378000E+03 5.310313E-01 4.292845E+02 6.296000E+03 5.257633E-01 4.296388E+02 6.184000E+03 5.212147E-01 4.299931E+02 6.175000E+03 5.153747E-01 4.303360E+02 6.206000E+03 5.765028E-01 4.306902E+02 6.241000E+03 5.850347E-01 4.310445E+02 6.165000E+03 5.471287E-01 4.313988E+02 6.330000E+03 5.668398E-01 4.317531E+02 6.185000E+03 5.328556E-01 4.320960E+02 6.183000E+03 5.759621E-01 4.324503E+02 6.165000E+03 5.648115E-01 4.328045E+02 6.086000E+03 5.612831E-01 4.331588E+02 6.034000E+03 5.663589E-01 4.335131E+02 6.093000E+03 5.439759E-01 4.338560E+02 6.085000E+03 5.778133E-01 4.342103E+02 5.947000E+03 5.299471E-01 4.345645E+02 6.031000E+03 5.646942E-01 4.349188E+02 5.979000E+03 5.645306E-01 4.352731E+02 5.836000E+03 4.932590E-01 4.356160E+02 5.801000E+03 4.874808E-01 4.359703E+02 5.891000E+03 5.529293E-01 4.363246E+02 5.939000E+03 5.578213E-01 4.366788E+02 5.694000E+03 4.820400E-01 4.370331E+02 5.878000E+03 5.446078E-01 4.373874E+02 5.747000E+03 5.286042E-01 4.377303E+02 5.705000E+03 5.041878E-01 4.380846E+02 5.858000E+03 5.386726E-01 4.384388E+02 5.790000E+03 5.094684E-01 4.387931E+02 5.704000E+03 5.034106E-01 4.391474E+02 5.721000E+03 5.594753E-01 4.394903E+02 5.597000E+03 4.855626E-01 4.398446E+02 5.697000E+03 5.438840E-01