********************* Core Excitation Data ******************** **************** A.P. Hitchcock & D.C. Mancini **************** * * Formula: H2Si(NtBuCH=CHNtBu) * Name: unsaturated SiH2 silylene * Edge: N 1s * Alpha Formula: C10H22N2Si * Data Source: Hitchcock * Filename: uq-0nnkk.os * Ref. Code: UH+98 * Write Date: 08/05/98 * Reference: Organometallics 17 (1998) 2352. * Source and Purity: Denk, distilled under vacuum * Acquisition Mode: EELS, 2 deg, 2500eV CRE mode, 0.7eV fwhm *-------------------------------------------------------------- * No. of Spectra: 2 name1- 0uqn13 name2- 0uqn.os * E (eV) Raw data Osc. Str. per atom (E-2) *-------------------------------------------------------------- 3.914579E+02 3.183127E+03 -2.684296E-02 3.916523E+02 3.194682E+03 5.007112E-03 3.918580E+02 3.165822E+03 -6.644727E-03 3.920524E+02 3.131788E+03 -1.472866E-02 3.922582E+02 3.239570E+03 1.566098E-02 3.924525E+02 3.225303E+03 3.720070E-02 3.926583E+02 3.160595E+03 5.062391E-03 3.928526E+02 3.184418E+03 1.426225E-02 3.930584E+02 3.177795E+03 2.781674E-02 3.932527E+02 3.104504E+03 -1.038439E-03 3.934585E+02 3.040385E+03 -3.008611E-02 3.936529E+02 3.091364E+03 1.662292E-02 3.938587E+02 3.137314E+03 -4.530931E-02 3.940530E+02 3.119785E+03 -5.463157E-03 3.942588E+02 3.044167E+03 -3.123214E-03 3.944531E+02 3.098369E+03 3.856143E-03 3.946589E+02 3.079149E+03 2.240541E-02 3.948532E+02 3.027109E+03 -3.212103E-02 3.950590E+02 3.076695E+03 1.297457E-02 3.952534E+02 3.072989E+03 2.725014E-02 3.954592E+02 3.046349E+03 -8.702355E-03 3.956535E+02 3.061543E+03 -1.235762E-02 3.958593E+02 3.043351E+03 8.174253E-03 3.960536E+02 3.029397E+03 -1.047866E-02 3.962594E+02 3.007572E+03 -3.812217E-03 3.964537E+02 3.029880E+03 1.119135E-02 3.966595E+02 2.985637E+03 -2.821110E-02 3.968539E+02 3.060991E+03 1.145935E-02 3.970597E+02 2.965773E+03 7.699947E-03 3.972540E+02 3.051573E+03 -2.037147E-03 3.973577E+02 3.037478E+03 -1.748763E-02 3.974606E+02 3.023110E+03 -3.672343E-02 3.975521E+02 3.002826E+03 4.239388E-03 3.976550E+02 3.032762E+03 2.521917E-02 3.977579E+02 3.013389E+03 2.715464E-02 3.978607E+02 3.039910E+03 -1.587223E-02 3.979522E+02 2.996782E+03 2.430584E-02 3.980551E+02 2.933802E+03 -2.285430E-02 3.981580E+02 2.970526E+03 2.174997E-02 3.982609E+02 2.970421E+03 1.947666E-02 3.983523E+02 2.985891E+03 -1.508352E-02 3.984552E+02 3.025967E+03 1.040660E-03 3.985581E+02 2.985750E+03 -1.391429E-02 3.986610E+02 2.942059E+03 2.092425E-03 3.987524E+02 2.931962E+03 3.987428E-03 3.988553E+02 2.972966E+03 -2.947262E-03 3.989582E+02 2.993380E+03 -1.581942E-02 3.990611E+02 2.975649E+03 1.420697E-02 3.991526E+02 2.953132E+03 2.178476E-02 3.992555E+02 2.950183E+03 1.802462E-02 3.993584E+02 2.943905E+03 4.740864E-02 3.994612E+02 2.959552E+03 4.690497E-03 3.995527E+02 2.971740E+03 2.238271E-02 3.996556E+02 3.001803E+03 4.339358E-02 3.997585E+02 3.059093E+03 8.899828E-02 3.998614E+02 3.075701E+03 1.377413E-01 3.999528E+02 3.159281E+03 1.951407E-01 4.000557E+02 3.173262E+03 1.964464E-01 4.001586E+02 3.237345E+03 3.011594E-01 4.002615E+02 3.344158E+03 4.355085E-01 4.003529E+02 3.371641E+03 5.418846E-01 4.004558E+02 3.422103E+03 6.731361E-01 4.005587E+02 3.480209E+03 7.406489E-01 4.006616E+02 3.636884E+03 8.930097E-01 4.007531E+02 3.728935E+03 9.785466E-01 4.008560E+02 3.760875E+03 1.125884E+00 4.009589E+02 3.774406E+03 1.146411E+00 4.010617E+02 3.776975E+03 1.142263E+00 4.011532E+02 3.738784E+03 1.185861E+00 4.012561E+02 3.604089E+03 1.105090E+00 4.013590E+02 3.583619E+03 1.074696E+00 4.014619E+02 3.604080E+03 1.063249E+00 4.015533E+02 3.539651E+03 9.710810E-01 4.016562E+02 3.495065E+03 9.014634E-01 4.017591E+02 3.496105E+03 8.536041E-01 4.018620E+02 3.437765E+03 7.801856E-01 4.019534E+02 3.393065E+03 7.384965E-01 4.020563E+02 3.447197E+03 7.152798E-01 4.021592E+02 3.483121E+03 6.962507E-01 4.022507E+02 3.442620E+03 6.712337E-01 4.023536E+02 3.487478E+03 7.658525E-01 4.024565E+02 3.590111E+03 8.043606E-01 4.025594E+02 3.600421E+03 8.312981E-01 4.026508E+02 3.545317E+03 8.455873E-01 4.027537E+02 3.550302E+03 8.610175E-01 4.028566E+02 3.632788E+03 9.618096E-01 4.029595E+02 3.656534E+03 1.015951E+00 4.030509E+02 3.706923E+03 1.094535E+00 4.031538E+02 3.719546E+03 1.117298E+00 4.032567E+02 3.690739E+03 1.152188E+00 4.033596E+02 3.638819E+03 1.137546E+00 4.034510E+02 3.727464E+03 1.169274E+00 4.035539E+02 3.805361E+03 1.172943E+00 4.036568E+02 3.781197E+03 1.233848E+00 4.037597E+02 3.785315E+03 1.238717E+00 4.038512E+02 3.727675E+03 1.262592E+00 4.039541E+02 3.728539E+03 1.303499E+00 4.040569E+02 3.771498E+03 1.270759E+00 4.041599E+02 3.827348E+03 1.314775E+00 4.042513E+02 3.885787E+03 1.282226E+00 4.043542E+02 3.853241E+03 1.215757E+00 4.044571E+02 3.798734E+03 1.188287E+00 4.045600E+02 3.835167E+03 1.193843E+00 4.046514E+02 3.832837E+03 1.249452E+00 4.047543E+02 3.812402E+03 1.300359E+00 4.048572E+02 3.792425E+03 1.285993E+00 4.049601E+02 3.823404E+03 1.317750E+00 4.050515E+02 3.863741E+03 1.347668E+00 4.051544E+02 3.846033E+03 1.350523E+00 4.052573E+02 3.856747E+03 1.365449E+00 4.053602E+02 3.869916E+03 1.383504E+00 4.054517E+02 3.880793E+03 1.366538E+00 4.055546E+02 3.798957E+03 1.324239E+00 4.056574E+02 3.769675E+03 1.306156E+00 4.057603E+02 3.827085E+03 1.360325E+00 4.058518E+02 3.863972E+03 1.359893E+00 4.059547E+02 3.892118E+03 1.345350E+00 4.060576E+02 3.792169E+03 1.333112E+00 4.061605E+02 3.688874E+03 1.301007E+00 4.062519E+02 3.705216E+03 1.284704E+00 4.063548E+02 3.680535E+03 1.259822E+00 4.064577E+02 3.697766E+03 1.282319E+00 4.065606E+02 3.687901E+03 1.246861E+00 4.066520E+02 3.611078E+03 1.214283E+00 4.067549E+02 3.641384E+03 1.235832E+00 4.068578E+02 3.663271E+03 1.262761E+00 4.069607E+02 3.693690E+03 1.134582E+00 4.070522E+02 3.711048E+03 1.176435E+00 4.071551E+02 3.652832E+03 1.121830E+00 4.072579E+02 3.594372E+03 1.078047E+00 4.073608E+02 3.585639E+03 1.153093E+00 4.074523E+02 3.545437E+03 1.122379E+00 4.075552E+02 3.531684E+03 1.073782E+00 4.076581E+02 3.593066E+03 1.101208E+00 4.077610E+02 3.587987E+03 1.076708E+00 4.078524E+02 3.516795E+03 1.066578E+00 4.079553E+02 3.477021E+03 1.063327E+00 4.080582E+02 3.571405E+03 1.056595E+00 4.081611E+02 3.621729E+03 1.120748E+00 4.082525E+02 3.566805E+03 1.104124E+00 4.083554E+02 3.462560E+03 1.089857E+00 4.084583E+02 3.413903E+03 1.081306E+00 4.085612E+02 3.507518E+03 1.088418E+00 4.086526E+02 3.550464E+03 1.119077E+00 4.087556E+02 3.557022E+03 1.065398E+00 4.088584E+02 3.556767E+03 1.035540E+00 4.089613E+02 3.515495E+03 1.025772E+00 4.090528E+02 3.536149E+03 1.046248E+00 4.091557E+02 3.541974E+03 1.077472E+00 4.092585E+02 3.471508E+03 1.020991E+00 4.094511E+02 3.437864E+03 1.027066E+00 4.096569E+02 3.364538E+03 9.791516E-01 4.098513E+02 3.411530E+03 1.015515E+00 4.100570E+02 3.424348E+03 9.929718E-01 4.102514E+02 3.446679E+03 9.541296E-01 4.104572E+02 3.354180E+03 9.613064E-01 4.106515E+02 3.313261E+03 9.393568E-01 4.108573E+02 3.332314E+03 9.901651E-01 4.110516E+02 3.316989E+03 9.637678E-01 4.112574E+02 3.305894E+03 9.293176E-01 4.114518E+02 3.256548E+03 8.968286E-01 4.116575E+02 3.330658E+03 8.862759E-01 4.118519E+02 3.291663E+03 8.729988E-01 4.120576E+02 3.213635E+03 8.412437E-01 4.122520E+02 3.153972E+03 8.838911E-01 4.124578E+02 3.199394E+03 8.795621E-01 4.126521E+02 3.285233E+03 9.044825E-01 4.128579E+02 3.233841E+03 8.564402E-01 4.130522E+02 3.137168E+03 8.278459E-01 4.132580E+02 3.190007E+03 8.597619E-01 4.134524E+02 3.215202E+03 9.218888E-01 4.136581E+02 3.226098E+03 9.089152E-01 4.138525E+02 3.223130E+03 8.957852E-01 4.140583E+02 3.205457E+03 8.641852E-01 4.142526E+02 3.189261E+03 8.822231E-01 4.144584E+02 3.172566E+03 8.553185E-01 4.146527E+02 3.147720E+03 8.635302E-01 4.148585E+02 3.146214E+03 8.792023E-01 4.150529E+02 3.150202E+03 8.595156E-01 4.152586E+02 3.116045E+03 8.061370E-01 4.154530E+02 3.142685E+03 8.081880E-01 4.156588E+02 3.158332E+03 8.319062E-01 4.158531E+02 3.150929E+03 8.037115E-01 4.160589E+02 3.152663E+03 8.061774E-01 4.162532E+02 3.052751E+03 7.559619E-01 4.164590E+02 3.009005E+03 7.620127E-01 4.166534E+02 3.012874E+03 7.685342E-01 4.168591E+02 2.997134E+03 7.645681E-01 4.170535E+02 3.046325E+03 7.582158E-01 4.172592E+02 2.991442E+03 7.644038E-01 4.174536E+02 3.025769E+03 7.882825E-01 4.176594E+02 3.049886E+03 7.870139E-01 4.178537E+02 3.015049E+03 7.354883E-01 4.180595E+02 2.920401E+03 7.112741E-01 4.182538E+02 2.955704E+03 7.315772E-01 4.184596E+02 2.991759E+03 7.028818E-01 4.186540E+02 3.004074E+03 7.456274E-01 4.188597E+02 2.984474E+03 7.286837E-01 4.190541E+02 2.981669E+03 6.948997E-01 4.192599E+02 2.947316E+03 7.296953E-01 4.196111E+02 2.855975E+03 6.785561E-01 4.199541E+02 2.790626E+03 6.837719E-01 4.203085E+02 2.836372E+03 6.170905E-01 4.206629E+02 2.887305E+03 7.046728E-01 4.210173E+02 2.849148E+03 6.543235E-01 4.213717E+02 2.831706E+03 6.359541E-01 4.217146E+02 2.842530E+03 6.222962E-01 4.220690E+02 2.821941E+03 6.071138E-01 4.224234E+02 2.741687E+03 6.206957E-01 4.227778E+02 2.716470E+03 6.000355E-01 4.231322E+02 2.710101E+03 6.026950E-01 4.234752E+02 2.738105E+03 6.033632E-01 4.238296E+02 2.716982E+03 5.879236E-01 4.241840E+02 2.707366E+03 5.997279E-01 4.245384E+02 2.681331E+03 5.845290E-01 4.248928E+02 2.690376E+03 5.587335E-01 4.252357E+02 2.679636E+03 5.304008E-01 4.255901E+02 2.659269E+03 5.842192E-01 4.259445E+02 2.707930E+03 5.771574E-01 4.262989E+02 2.665202E+03 5.614548E-01 4.266533E+02 2.603173E+03 5.489192E-01 4.269962E+02 2.611367E+03 5.694708E-01 4.273506E+02 2.587035E+03 5.825897E-01 4.277050E+02 2.590078E+03 5.232028E-01 4.280594E+02 2.590939E+03 5.493520E-01 4.284138E+02 2.571560E+03 5.439492E-01 4.287568E+02 2.563757E+03 5.181397E-01 4.291112E+02 2.565078E+03 5.061687E-01 4.294656E+02 2.581704E+03 5.548098E-01 4.298200E+02 2.575479E+03 5.703188E-01 4.301744E+02 2.519082E+03 5.222720E-01 4.305173E+02 2.487564E+03 5.335413E-01 4.308717E+02 2.498566E+03 5.159661E-01 4.312261E+02 2.473817E+03 5.068646E-01 4.315805E+02 2.501321E+03 5.152630E-01 4.319349E+02 2.492981E+03 5.209714E-01 4.322779E+02 2.477843E+03 5.452378E-01 4.326323E+02 2.511444E+03 5.510665E-01 4.329867E+02 2.473488E+03 5.148262E-01 4.333411E+02 2.453417E+03 4.949638E-01 4.336955E+02 2.503487E+03 5.631674E-01 4.340499E+02 2.500101E+03 5.310777E-01 4.343928E+02 2.443731E+03 5.065910E-01 4.347472E+02 2.430008E+03 5.319989E-01 4.351016E+02 2.439696E+03 5.234029E-01 4.354560E+02 2.384157E+03 4.808459E-01 4.358104E+02 2.355924E+03 5.049588E-01 4.361534E+02 2.402216E+03 5.206425E-01 4.365078E+02 2.451426E+03 5.158057E-01 4.368622E+02 2.417914E+03 5.410072E-01 4.372166E+02 2.378817E+03 5.251358E-01 4.375710E+02 2.407817E+03 5.377274E-01 4.379139E+02 2.395079E+03 5.018355E-01 4.382683E+02 2.345704E+03 5.241021E-01 4.386227E+02 2.360782E+03 4.889348E-01 4.389771E+02 2.357122E+03 5.028186E-01 4.393315E+02 2.338245E+03 5.533878E-01 4.396745E+02 2.338493E+03 5.635720E-01 4.400288E+02 2.299140E+03 5.183487E-01 4.403832E+02 2.305347E+03 4.850562E-01 4.407376E+02 2.299906E+03 5.083029E-01 4.410920E+02 2.233566E+03 5.167335E-01 4.414350E+02 2.252539E+03 5.325412E-01 4.417894E+02 2.292808E+03 5.071437E-01 4.421438E+02 2.318253E+03 5.349052E-01 4.424982E+02 2.305782E+03 5.344509E-01 4.428526E+02 2.311994E+03 5.361201E-01 4.431956E+02 2.278822E+03 5.198306E-01 4.435499E+02 2.237235E+03 5.338754E-01 4.439043E+02 2.230061E+03 5.457883E-01