********************* Core Excitation Data ******************** **************** A.P. Hitchcock & D.C. Mancini **************** * * Formula: H2Si(NtBuCH=CHNtBu) * Name: unsaturated SiH2 silylene * Edge: C 1s * Alpha Formula: C10H22N2Si * Data Source: Hitchcock * Filename: uq-0cckk.os * Ref. Code: UH+98 * Write Date: 08/05/98 * Reference: Organometallics 17 (1998) 2352. * Source and Purity: Denk, distilled under vacuum * Acquisition Mode: EELS, 2 deg, 2500eV CRE mode, 0.7eV fwhm *-------------------------------------------------------------- * No. of Spectra: 2 name1- 0uqc4 name2- 0uqc.os * E (eV) Raw data Osc. Str. per atom (E-2) *-------------------------------------------------------------- 2.795504E+02 1.958000E+03 -3.758027E-03 2.796296E+02 2.000110E+03 -5.055678E-03 2.798233E+02 2.019674E+03 -2.411913E-04 2.800284E+02 1.967190E+03 1.736138E-03 2.802220E+02 1.987307E+03 5.353520E-03 2.804271E+02 1.959633E+03 -2.170119E-03 2.806208E+02 1.999813E+03 -1.932671E-03 2.808259E+02 1.982240E+03 2.360134E-03 2.810309E+02 2.001564E+03 -4.294004E-03 2.812246E+02 1.939070E+03 -3.446006E-03 2.814297E+02 1.907092E+03 -1.804744E-02 2.816234E+02 1.918661E+03 1.410310E-03 2.818285E+02 1.948008E+03 2.474765E-03 2.820221E+02 1.964145E+03 -1.030668E-03 2.822222E+02 1.913929E+03 1.187961E-02 2.823247E+02 1.872448E+03 -1.220676E-02 2.824272E+02 1.881617E+03 -6.757636E-03 2.825298E+02 1.910130E+03 -4.745101E-03 2.826209E+02 1.910539E+03 9.850091E-04 2.827235E+02 1.898350E+03 1.438372E-03 2.828260E+02 1.912386E+03 1.163513E-02 2.829286E+02 1.936400E+03 -2.844660E-03 2.830311E+02 1.931492E+03 -3.484432E-04 2.831222E+02 1.917386E+03 5.411653E-03 2.832248E+02 1.922417E+03 1.533478E-02 2.833273E+02 1.935413E+03 7.748487E-03 2.834298E+02 1.909496E+03 5.362928E-03 2.835210E+02 1.873246E+03 7.509776E-03 2.836235E+02 1.855846E+03 5.276928E-03 2.837260E+02 1.847346E+03 -4.094990E-03 2.838286E+02 1.856893E+03 -2.853724E-03 2.839311E+02 1.873294E+03 8.079465E-03 2.840222E+02 1.876362E+03 1.198603E-02 2.841248E+02 1.876862E+03 -6.648545E-03 2.842273E+02 1.905579E+03 1.641881E-02 2.843299E+02 1.945102E+03 9.710699E-03 2.844210E+02 1.941078E+03 1.618613E-02 2.845235E+02 1.916722E+03 -4.116685E-03 2.846261E+02 1.907826E+03 2.367919E-02 2.847286E+02 1.904828E+03 1.070661E-02 2.848311E+02 1.898638E+03 9.085483E-03 2.849223E+02 1.892045E+03 6.731410E-04 2.850248E+02 1.931631E+03 2.071288E-02 2.851273E+02 1.989114E+03 2.616693E-02 2.852299E+02 2.000782E+03 4.771910E-02 2.853210E+02 1.995607E+03 5.202701E-02 2.854236E+02 2.098704E+03 5.091832E-02 2.855261E+02 2.243096E+03 9.756351E-02 2.856287E+02 2.252855E+03 1.192686E-01 2.857312E+02 2.358957E+03 1.628406E-01 2.858223E+02 2.481273E+03 2.721187E-01 2.859249E+02 2.684626E+03 3.342262E-01 2.860274E+02 2.941311E+03 4.423387E-01 2.861299E+02 3.101062E+03 5.386563E-01 2.862211E+02 3.256106E+03 5.747814E-01 2.863236E+02 3.342692E+03 6.320621E-01 2.864261E+02 3.419575E+03 6.596713E-01 2.865287E+02 3.562794E+03 6.435093E-01 2.866312E+02 3.481865E+03 6.512862E-01 2.867224E+02 3.445589E+03 6.442645E-01 2.868249E+02 3.549132E+03 6.473163E-01 2.869274E+02 3.533810E+03 6.606765E-01 2.870300E+02 3.588612E+03 7.329983E-01 2.871211E+02 3.694864E+03 7.417472E-01 2.872237E+02 3.857749E+03 7.909920E-01 2.873262E+02 3.991320E+03 8.818706E-01 2.874287E+02 4.325250E+03 9.688200E-01 2.875313E+02 4.710661E+03 1.082427E+00 2.876224E+02 4.961023E+03 1.213034E+00 2.877249E+02 5.173201E+03 1.312424E+00 2.878275E+02 5.281667E+03 1.372084E+00 2.879300E+02 5.275534E+03 1.388261E+00 2.880211E+02 5.286205E+03 1.335173E+00 2.881237E+02 5.134464E+03 1.264148E+00 2.882262E+02 4.868560E+03 1.197285E+00 2.883288E+02 4.601066E+03 1.104426E+00 2.884313E+02 4.530039E+03 1.031958E+00 2.885224E+02 4.417825E+03 1.027785E+00 2.886250E+02 4.246280E+03 9.841964E-01 2.887275E+02 4.230083E+03 9.674804E-01 2.888300E+02 4.291759E+03 9.763836E-01 2.889212E+02 4.274576E+03 9.968151E-01 2.890237E+02 4.317485E+03 1.034634E+00 2.891263E+02 4.489614E+03 1.049805E+00 2.892288E+02 4.564124E+03 1.090255E+00 2.893313E+02 4.634203E+03 1.101491E+00 2.894225E+02 4.624621E+03 1.139380E+00 2.895250E+02 4.731668E+03 1.189588E+00 2.896275E+02 4.783682E+03 1.163178E+00 2.897301E+02 4.793023E+03 1.177210E+00 2.898212E+02 4.779098E+03 1.184697E+00 2.899238E+02 4.747327E+03 1.207358E+00 2.900263E+02 4.840230E+03 1.237308E+00 2.901288E+02 4.861188E+03 1.240157E+00 2.902314E+02 4.899744E+03 1.243517E+00 2.903225E+02 5.004977E+03 1.239429E+00 2.904250E+02 5.056752E+03 1.275100E+00 2.905276E+02 5.101065E+03 1.310162E+00 2.906301E+02 5.028964E+03 1.296308E+00 2.907213E+02 5.079758E+03 1.290207E+00 2.908238E+02 5.060913E+03 1.360359E+00 2.909263E+02 4.995491E+03 1.327981E+00 2.910289E+02 5.163309E+03 1.361212E+00 2.911314E+02 5.237985E+03 1.381734E+00 2.912225E+02 5.150347E+03 1.401067E+00 2.913251E+02 5.088090E+03 1.376617E+00 2.914276E+02 5.166731E+03 1.393790E+00 2.915302E+02 5.153831E+03 1.405182E+00 2.916213E+02 5.195735E+03 1.409545E+00 2.917238E+02 5.286572E+03 1.411548E+00 2.918264E+02 5.193991E+03 1.434813E+00 2.919289E+02 5.225055E+03 1.453831E+00 2.920314E+02 5.177939E+03 1.411042E+00 2.921226E+02 5.214080E+03 1.447230E+00 2.922251E+02 5.321131E+03 1.430855E+00 2.923276E+02 5.365320E+03 1.450104E+00 2.924302E+02 5.343377E+03 1.456630E+00 2.925213E+02 5.293054E+03 1.487810E+00 2.926239E+02 5.290939E+03 1.466911E+00 2.927264E+02 5.178271E+03 1.462051E+00 2.928289E+02 5.248625E+03 1.490934E+00 2.929201E+02 5.326023E+03 1.450010E+00 2.930226E+02 5.290162E+03 1.470086E+00 2.931252E+02 5.364855E+03 1.460863E+00 2.932277E+02 5.322734E+03 1.453705E+00 2.933302E+02 5.221648E+03 1.469662E+00 2.934214E+02 5.213492E+03 1.437391E+00 2.935239E+02 5.227789E+03 1.492215E+00 2.936264E+02 5.233520E+03 1.494296E+00 2.937290E+02 5.294633E+03 1.480316E+00 2.938201E+02 5.197416E+03 1.468194E+00 2.939226E+02 5.172046E+03 1.458006E+00 2.940252E+02 5.167069E+03 1.454800E+00 2.941277E+02 5.051534E+03 1.452110E+00 2.942303E+02 5.044769E+03 1.415732E+00 2.943214E+02 5.100679E+03 1.430877E+00 2.944239E+02 5.092266E+03 1.420768E+00 2.945265E+02 5.062551E+03 1.414333E+00 2.946290E+02 5.062521E+03 1.392739E+00 2.947202E+02 5.003956E+03 1.363148E+00 2.948227E+02 4.909026E+03 1.400030E+00 2.949252E+02 4.859303E+03 1.438393E+00 2.950278E+02 4.835997E+03 1.366003E+00 2.952234E+02 4.792033E+03 1.365852E+00 2.954284E+02 4.828551E+03 1.326112E+00 2.956221E+02 4.686432E+03 1.323883E+00 2.958272E+02 4.620227E+03 1.300636E+00 2.960209E+02 4.634710E+03 1.301192E+00 2.962260E+02 4.548447E+03 1.290311E+00 2.964310E+02 4.481070E+03 1.274902E+00 2.966247E+02 4.532132E+03 1.242911E+00 2.968298E+02 4.569858E+03 1.237944E+00 2.970234E+02 4.480214E+03 1.205209E+00 2.972285E+02 4.463752E+03 1.205730E+00 2.974222E+02 4.347592E+03 1.181296E+00 2.976273E+02 4.305030E+03 1.183751E+00 2.978209E+02 4.331257E+03 1.190386E+00 2.980260E+02 4.294806E+03 1.173943E+00 2.982311E+02 4.180718E+03 1.174007E+00 2.984247E+02 4.224616E+03 1.157826E+00 2.986298E+02 4.260294E+03 1.151079E+00 2.988235E+02 4.278458E+03 1.158233E+00 2.990286E+02 4.229835E+03 1.154383E+00 2.992223E+02 4.231914E+03 1.149052E+00 2.994273E+02 4.190715E+03 1.119177E+00 2.996210E+02 4.074765E+03 1.117071E+00 2.998261E+02 4.015727E+03 1.110311E+00 3.000312E+02 4.090038E+03 1.123900E+00 3.002248E+02 4.128455E+03 1.083345E+00 3.004299E+02 4.026388E+03 1.103243E+00 3.006236E+02 3.980451E+03 1.145772E+00 3.008286E+02 3.913488E+03 1.106486E+00 3.010223E+02 3.907352E+03 1.104844E+00 3.012274E+02 3.904835E+03 1.111039E+00 3.014211E+02 3.922456E+03 1.091928E+00 3.016262E+02 3.891896E+03 1.054662E+00 3.018312E+02 3.844370E+03 1.077545E+00 3.020249E+02 3.799469E+03 1.062211E+00 3.022300E+02 3.805949E+03 1.045462E+00 3.024236E+02 3.818693E+03 1.066381E+00 3.026287E+02 3.808273E+03 1.046147E+00 3.028224E+02 3.762291E+03 1.053629E+00 3.030275E+02 3.713600E+03 1.019182E+00 3.032212E+02 3.674407E+03 1.019377E+00 3.034262E+02 3.633920E+03 1.015134E+00 3.036313E+02 3.607898E+03 9.788677E-01 3.038250E+02 3.605192E+03 9.966335E-01 3.040300E+02 3.602330E+03 9.782634E-01 3.042237E+02 3.586731E+03 1.003212E+00 3.044288E+02 3.568319E+03 9.816855E-01 3.046225E+02 3.568866E+03 9.479299E-01 3.048275E+02 3.604854E+03 9.854955E-01 3.050212E+02 3.638855E+03 9.915958E-01 3.052263E+02 3.565269E+03 9.278570E-01 3.054314E+02 3.469115E+03 9.201790E-01 3.056250E+02 3.419965E+03 9.421843E-01 3.058301E+02 3.450241E+03 9.307775E-01 3.060238E+02 3.478833E+03 9.213306E-01 3.062289E+02 3.459000E+03 9.143447E-01 3.064225E+02 3.430551E+03 9.305815E-01 3.066276E+02 3.400984E+03 9.194388E-01 3.068213E+02 3.373936E+03 8.927094E-01 3.070264E+02 3.345294E+03 9.158473E-01 3.072314E+02 3.332951E+03 9.162846E-01 3.074251E+02 3.323290E+03 9.328458E-01 3.076302E+02 3.295730E+03 8.925455E-01 3.078239E+02 3.243558E+03 8.979600E-01 3.080289E+02 3.188353E+03 8.863704E-01 3.082226E+02 3.196591E+03 8.807879E-01 3.084277E+02 3.214184E+03 8.839333E-01 3.086214E+02 3.221899E+03 8.704901E-01 3.088264E+02 3.212494E+03 8.490919E-01 3.090201E+02 3.203606E+03 8.508319E-01 3.092252E+02 3.168751E+03 8.638077E-01 3.094303E+02 3.128652E+03 8.487297E-01 3.096239E+02 3.090804E+03 8.186715E-01 3.098290E+02 3.050708E+03 8.764776E-01 3.100227E+02 3.012843E+03 8.565101E-01 3.103259E+02 2.993695E+03 8.355342E-01 3.106221E+02 3.010439E+03 8.552173E-01 3.109297E+02 3.144173E+03 8.429631E-01 3.112259E+02 3.139850E+03 8.528884E-01 3.115335E+02 3.042266E+03 8.353837E-01 3.118297E+02 2.952776E+03 8.188742E-01 3.121259E+02 2.899671E+03 8.012285E-01 3.124335E+02 2.956124E+03 8.149760E-01 3.127298E+02 2.962809E+03 8.174053E-01 3.130374E+02 2.936421E+03 8.043032E-01 3.133336E+02 2.924961E+03 7.966413E-01 3.136298E+02 2.917892E+03 8.023668E-01 3.139374E+02 2.921573E+03 7.905548E-01 3.142336E+02 2.887337E+03 8.106321E-01 3.145412E+02 2.825363E+03 8.010843E-01 3.148374E+02 2.828692E+03 7.849715E-01 3.151337E+02 2.824561E+03 8.070806E-01 3.154413E+02 2.785630E+03 7.839608E-01 3.157375E+02 2.778016E+03 7.738453E-01 3.160451E+02 2.787834E+03 7.992066E-01 3.163413E+02 2.744462E+03 8.041192E-01 3.166375E+02 2.717970E+03 7.566116E-01 3.169451E+02 2.735764E+03 7.619746E-01 3.172413E+02 2.695395E+03 7.906597E-01 3.175490E+02 2.619283E+03 7.989517E-01 3.178452E+02 2.684178E+03 7.951491E-01 3.181414E+02 2.719663E+03 7.939403E-01 3.184490E+02 2.675471E+03 7.814397E-01 3.187452E+02 2.670529E+03 7.757681E-01 3.190528E+02 2.687708E+03 7.604809E-01 3.193490E+02 2.664241E+03 7.653134E-01 3.196452E+02 2.645865E+03 7.890035E-01 3.199528E+02 2.639115E+03 7.662606E-01 3.202491E+02 2.647768E+03 7.700016E-01 3.205566E+02 2.662855E+03 7.615876E-01 3.208529E+02 2.607294E+03 7.832405E-01 3.211491E+02 2.561846E+03 7.623124E-01 3.214567E+02 2.536077E+03 7.454422E-01 3.217529E+02 2.550718E+03 7.281200E-01 3.220605E+02 2.584443E+03 7.667581E-01 3.223567E+02 2.557257E+03 7.655007E-01 3.226529E+02 2.522697E+03 7.371336E-01 3.229605E+02 2.471149E+03 7.534728E-01 3.232567E+02 2.476924E+03 7.464169E-01 3.235644E+02 2.509545E+03 7.336993E-01 3.238606E+02 2.487778E+03 7.315957E-01 3.241568E+02 2.473566E+03 7.587723E-01 3.244644E+02 2.472339E+03 7.429472E-01 3.247606E+02 2.431978E+03 7.410530E-01 3.250682E+02 2.377419E+03 7.134454E-01 3.253644E+02 2.384510E+03 7.613446E-01 3.256606E+02 2.395283E+03 7.400479E-01 3.259683E+02 2.413082E+03 7.541482E-01 3.262645E+02 2.387241E+03 7.251782E-01 3.265545E+02 2.345000E+03 7.331525E-01