********************* Core Excitation Data ******************** **************** A.P. Hitchcock & D.C. Mancini **************** * * Formula: Si(NtBuCH=CHNtBu) * Name: silylene * Edge: Si 2p * Alpha Formula: C10H20N2Si * Data Source: Hitchcock * Filename: uo-0sill.os * Ref. Code: UH+98 * Write Date: 08/05/98 * Reference: Organometallics 17 (1998) 2352. * Source and Purity: Denk, sublimed under argon * Acquisition Mode: EELS, 2 deg, 2500eV CRE mode, 0.7eV fwhm *-------------------------------------------------------------- * No. of Spectra: 2 name1- 0uol name2- 0uol.os * E (eV) Raw data Osc. Str. per atom (E-2) *-------------------------------------------------------------- 9.004537E+01 1.588377E+05 -3.130756E-02 9.025108E+01 1.573427E+05 -1.411099E-02 9.044537E+01 1.563310E+05 -4.703608E-02 9.065108E+01 1.554492E+05 4.134009E-04 9.084537E+01 1.538956E+05 1.264655E-02 9.105109E+01 1.525238E+05 -4.122245E-02 9.124537E+01 1.513885E+05 2.203591E-02 9.145108E+01 1.499681E+05 1.114342E-02 9.164537E+01 1.485742E+05 3.083936E-02 9.185108E+01 1.472963E+05 3.055319E-02 9.204537E+01 1.463687E+05 3.722287E-02 9.225108E+01 1.450529E+05 1.651355E-02 9.244537E+01 1.435662E+05 -2.059034E-02 9.265108E+01 1.434516E+05 3.182399E-02 9.284537E+01 1.413326E+05 -1.039420E-02 9.305109E+01 1.399680E+05 5.738126E-04 9.324537E+01 1.388830E+05 -9.258999E-03 9.345108E+01 1.377715E+05 -1.759483E-02 9.364537E+01 1.368930E+05 1.060729E-03 9.385108E+01 1.356173E+05 4.343572E-03 9.404537E+01 1.347002E+05 1.161234E-02 9.425108E+01 1.338746E+05 8.467252E-03 9.444537E+01 1.328491E+05 3.634165E-02 9.465108E+01 1.315839E+05 -1.511917E-04 9.484537E+01 1.303374E+05 -2.822813E-02 9.505109E+01 1.294284E+05 -7.048275E-03 9.524537E+01 1.289095E+05 4.404970E-03 9.545108E+01 1.272848E+05 -5.390076E-03 9.564537E+01 1.262520E+05 1.390814E-02 9.585108E+01 1.258258E+05 -1.968144E-03 9.604537E+01 1.246954E+05 -1.804971E-02 9.625108E+01 1.236411E+05 7.094893E-03 9.644537E+01 1.225024E+05 3.925356E-02 9.665108E+01 1.213144E+05 4.142181E-03 9.684537E+01 1.204948E+05 1.399406E-02 9.705109E+01 1.190234E+05 -3.844675E-02 9.724537E+01 1.187957E+05 -3.530653E-03 9.745108E+01 1.172437E+05 7.082603E-04 9.764537E+01 1.161470E+05 -3.084340E-02 9.785108E+01 1.153631E+05 -6.315410E-03 9.804537E+01 1.150986E+05 9.653789E-03 9.825108E+01 1.132526E+05 -4.233086E-02 9.844537E+01 1.129925E+05 2.414403E-02 9.865108E+01 1.116235E+05 1.436149E-02 9.884537E+01 1.111563E+05 -5.105349E-02 9.905109E+01 1.107216E+05 1.898248E-02 9.924537E+01 1.099006E+05 5.806220E-05 9.945108E+01 1.085143E+05 1.402257E-02 9.964537E+01 1.080965E+05 -1.197761E-03 9.985108E+01 1.073088E+05 3.321980E-02 1.000454E+02 1.063443E+05 2.875007E-02 1.002511E+02 1.056458E+05 6.428824E-02 1.004454E+02 1.059029E+05 1.786307E-01 1.006511E+02 1.055612E+05 2.619171E-01 1.008454E+02 1.047918E+05 3.007658E-01 1.010511E+02 1.040982E+05 3.226434E-01 1.011477E+02 1.037735E+05 2.745713E-01 1.012506E+02 1.031040E+05 2.876111E-01 1.013534E+02 1.022781E+05 2.111881E-01 1.014448E+02 1.021834E+05 2.283847E-01 1.015477E+02 1.019869E+05 2.334729E-01 1.016506E+02 1.014739E+05 2.338870E-01 1.017534E+02 1.013957E+05 2.773772E-01 1.018448E+02 1.011406E+05 2.767843E-01 1.019477E+02 1.015942E+05 3.992428E-01 1.020506E+02 1.014201E+05 4.764750E-01 1.021534E+02 1.021830E+05 6.340275E-01 1.022448E+02 1.027258E+05 7.511361E-01 1.023477E+02 1.037444E+05 9.002934E-01 1.024506E+02 1.043648E+05 1.103400E+00 1.025534E+02 1.046882E+05 1.238156E+00 1.026448E+02 1.057331E+05 1.401742E+00 1.027477E+02 1.070400E+05 1.596151E+00 1.028506E+02 1.076725E+05 1.793460E+00 1.029534E+02 1.084677E+05 1.986838E+00 1.030448E+02 1.091617E+05 2.127301E+00 1.031477E+02 1.092995E+05 2.242806E+00 1.032506E+02 1.094527E+05 2.339477E+00 1.033534E+02 1.095417E+05 2.413496E+00 1.034448E+02 1.093452E+05 2.420817E+00 1.035477E+02 1.085322E+05 2.332775E+00 1.036506E+02 1.076411E+05 2.294639E+00 1.037534E+02 1.071394E+05 2.162430E+00 1.038448E+02 1.066124E+05 2.156840E+00 1.039477E+02 1.062095E+05 2.142052E+00 1.040506E+02 1.057675E+05 2.175623E+00 1.041534E+02 1.053932E+05 2.153200E+00 1.042448E+02 1.052448E+05 2.182528E+00 1.043477E+02 1.052255E+05 2.234779E+00 1.044506E+02 1.047157E+05 2.217232E+00 1.045534E+02 1.046461E+05 2.251609E+00 1.046448E+02 1.044245E+05 2.287967E+00 1.047477E+02 1.041439E+05 2.287278E+00 1.048506E+02 1.039222E+05 2.320867E+00 1.049534E+02 1.036743E+05 2.336084E+00 1.050448E+02 1.031249E+05 2.305272E+00 1.051477E+02 1.029093E+05 2.277023E+00 1.052506E+02 1.024394E+05 2.280755E+00 1.053534E+02 1.016711E+05 2.223950E+00 1.054448E+02 1.007938E+05 2.153316E+00 1.055477E+02 1.006441E+05 2.148751E+00 1.056506E+02 1.005497E+05 2.156120E+00 1.057534E+02 1.001319E+05 2.128073E+00 1.058448E+02 9.972695E+04 2.108819E+00 1.059477E+02 9.926055E+04 2.102349E+00 1.060506E+02 9.896295E+04 2.116890E+00 1.061534E+02 9.882525E+04 2.180584E+00 1.062448E+02 9.874296E+04 2.206884E+00 1.063477E+02 9.880219E+04 2.241668E+00 1.064506E+02 9.848170E+04 2.252522E+00 1.065534E+02 9.825549E+04 2.292409E+00 1.066448E+02 9.841544E+04 2.355234E+00 1.067477E+02 9.811079E+04 2.374929E+00 1.068506E+02 9.754584E+04 2.380753E+00 1.069534E+02 9.798076E+04 2.484615E+00 1.070448E+02 9.779399E+04 2.448123E+00 1.071477E+02 9.720583E+04 2.478694E+00 1.072506E+02 9.716419E+04 2.448303E+00 1.073534E+02 9.724992E+04 2.506013E+00 1.074448E+02 9.658780E+04 2.489187E+00 1.075477E+02 9.635841E+04 2.485250E+00 1.076506E+02 9.589748E+04 2.489650E+00 1.077534E+02 9.593763E+04 2.560810E+00 1.078448E+02 9.602443E+04 2.546878E+00 1.079477E+02 9.570720E+04 2.549543E+00 1.080506E+02 9.532355E+04 2.543626E+00 1.081534E+02 9.532918E+04 2.573601E+00 1.082448E+02 9.502174E+04 2.592690E+00 1.083477E+02 9.497891E+04 2.614550E+00 1.084506E+02 9.462092E+04 2.613853E+00 1.085534E+02 9.473013E+04 2.706469E+00 1.086448E+02 9.512407E+04 2.735775E+00 1.087477E+02 9.470778E+04 2.756818E+00 1.088506E+02 9.413532E+04 2.774905E+00 1.089534E+02 9.408017E+04 2.782402E+00 1.090448E+02 9.418259E+04 2.866192E+00 1.091477E+02 9.415620E+04 2.841155E+00 1.092506E+02 9.366288E+04 2.856348E+00 1.093534E+02 9.364171E+04 2.891894E+00 1.094448E+02 9.346343E+04 2.925300E+00 1.095477E+02 9.273989E+04 2.874617E+00 1.096506E+02 9.294405E+04 2.914139E+00 1.097534E+02 9.273616E+04 2.962378E+00 1.098448E+02 9.252815E+04 2.925405E+00 1.099477E+02 9.274067E+04 2.988240E+00 1.100506E+02 9.228560E+04 3.010025E+00 1.103551E+02 9.233552E+04 3.054197E+00 1.106523E+02 9.174502E+04 3.135338E+00 1.109494E+02 9.102623E+04 3.174300E+00 1.112580E+02 9.057520E+04 3.209110E+00 1.115551E+02 9.038835E+04 3.270006E+00 1.118522E+02 8.917850E+04 3.246952E+00 1.121494E+02 8.862007E+04 3.332811E+00 1.124580E+02 8.854270E+04 3.319354E+00 1.127551E+02 8.687841E+04 3.325691E+00 1.130523E+02 8.619319E+04 3.318433E+00 1.133608E+02 8.548807E+04 3.337529E+00 1.136580E+02 8.495416E+04 3.289076E+00 1.139551E+02 8.440241E+04 3.324923E+00 1.142637E+02 8.300670E+04 3.237634E+00 1.145608E+02 8.239866E+04 3.291189E+00 1.148580E+02 8.203632E+04 3.299963E+00 1.151665E+02 8.122688E+04 3.298602E+00 1.154637E+02 8.055920E+04 3.285120E+00 1.157608E+02 8.064131E+04 3.362785E+00 1.160694E+02 7.962841E+04 3.381839E+00 1.163665E+02 7.876456E+04 3.374771E+00 1.166637E+02 7.884255E+04 3.455703E+00 1.169723E+02 7.870484E+04 3.500110E+00 1.172694E+02 7.806262E+04 3.503815E+00 1.175665E+02 7.794413E+04 3.590937E+00 1.178637E+02 7.712763E+04 3.600322E+00 1.181722E+02 7.719446E+04 3.687039E+00 1.184694E+02 7.668777E+04 3.732987E+00 1.187665E+02 7.617886E+04 3.775237E+00 1.190751E+02 7.554477E+04 3.766630E+00 1.193723E+02 7.564255E+04 3.888901E+00 1.196694E+02 7.568100E+04 3.946137E+00 1.199780E+02 7.519983E+04 4.007941E+00 1.202751E+02 7.496728E+04 4.114729E+00 1.205723E+02 7.471131E+04 4.119149E+00 1.208808E+02 7.453916E+04 4.165177E+00 1.211780E+02 7.439413E+04 4.267582E+00 1.214751E+02 7.416423E+04 4.351292E+00 1.217837E+02 7.384901E+04 4.389007E+00 1.220808E+02 7.367570E+04 4.429585E+00 1.223780E+02 7.310789E+04 4.481533E+00 1.226865E+02 7.317464E+04 4.553558E+00 1.229837E+02 7.296832E+04 4.604737E+00 1.232808E+02 7.281287E+04 4.671651E+00 1.235780E+02 7.275152E+04 4.758692E+00 1.238865E+02 7.246152E+04 4.788652E+00 1.241837E+02 7.197512E+04 4.776730E+00 1.244808E+02 7.139759E+04 4.876463E+00 1.247894E+02 7.131746E+04 4.917852E+00 1.250865E+02 7.122166E+04 4.976441E+00 1.253837E+02 7.073459E+04 4.946506E+00 1.256923E+02 7.011990E+04 4.955027E+00 1.259894E+02 7.021309E+04 5.029606E+00 1.262865E+02 6.967055E+04 5.021028E+00 1.265951E+02 6.905294E+04 5.017703E+00 1.268923E+02 6.840088E+04 5.001179E+00 1.271894E+02 6.803940E+04 5.016258E+00 1.274980E+02 6.791178E+04 5.055543E+00 1.277951E+02 6.737838E+04 5.050319E+00 1.280923E+02 6.687104E+04 5.025633E+00 1.284008E+02 6.607863E+04 4.960308E+00 1.286980E+02 6.567987E+04 4.964831E+00 1.289951E+02 6.532458E+04 4.987762E+00 1.293037E+02 6.477007E+04 4.986722E+00 1.296008E+02 6.394732E+04 4.949032E+00 1.298980E+02 6.363254E+04 4.908326E+00 1.301951E+02 6.342592E+04 4.908837E+00 1.305037E+02 6.261630E+04 4.886665E+00 1.308008E+02 6.150646E+04 4.840609E+00 1.310980E+02 6.152289E+04 4.830558E+00 1.314065E+02 6.111392E+04 4.811034E+00 1.317037E+02 6.047280E+04 4.791752E+00 1.320008E+02 5.957508E+04 4.752581E+00 1.323094E+02 5.933595E+04 4.719088E+00 1.326065E+02 5.884281E+04 4.686320E+00 1.329037E+02 5.812014E+04 4.659768E+00 1.332122E+02 5.778150E+04 4.613662E+00 1.335094E+02 5.735582E+04 4.659483E+00 1.338065E+02 5.713427E+04 4.672524E+00 1.341151E+02 5.640501E+04 4.620806E+00 1.344122E+02 5.577775E+04 4.564740E+00 1.347094E+02 5.530902E+04 4.552909E+00 1.350180E+02 5.502521E+04 4.519664E+00 1.353151E+02 5.491492E+04 4.561081E+00 1.356122E+02 5.460549E+04 4.542673E+00 1.359094E+02 5.363276E+04 4.457492E+00 1.362180E+02 5.307038E+04 4.423668E+00 1.365151E+02 5.322847E+04 4.501073E+00 1.368123E+02 5.244084E+04 4.435349E+00 1.371208E+02 5.212713E+04 4.447750E+00 1.374180E+02 5.164107E+04 4.437479E+00 1.377151E+02 5.147207E+04 4.400803E+00 1.380237E+02 5.098093E+04 4.409297E+00 1.383208E+02 5.083362E+04 4.419020E+00 1.386180E+02 5.032877E+04 4.377398E+00 1.389265E+02 4.995178E+04 4.391180E+00 1.392237E+02 4.945441E+04 4.409225E+00 1.395208E+02 4.897713E+04 4.341018E+00 1.398294E+02 4.890200E+04 4.315803E+00 1.401265E+02 4.820973E+04 4.259027E+00 1.404237E+02 4.764558E+04 4.260460E+00 1.407323E+02 4.776530E+04 4.292669E+00 1.410294E+02 4.767013E+04 4.332306E+00 1.413265E+02 4.722321E+04 4.301496E+00 1.416237E+02 4.676861E+04 4.299472E+00 1.419323E+02 4.654779E+04 4.293845E+00 1.422294E+02 4.629831E+04 4.318360E+00 1.425265E+02 4.586265E+04 4.255437E+00 1.428351E+02 4.569814E+04 4.277380E+00 1.431322E+02 4.505488E+04 4.261361E+00 1.434294E+02 4.487900E+04 4.219491E+00 1.437380E+02 4.472563E+04 4.248021E+00 1.440351E+02 4.440086E+04 4.250999E+00 1.443322E+02 4.417396E+04 4.279677E+00 1.446408E+02 4.350675E+04 4.229131E+00 1.449380E+02 4.379342E+04 4.243262E+00 1.452351E+02 4.305575E+04 4.211212E+00 1.455437E+02 4.282207E+04 4.184354E+00 1.458408E+02 4.261820E+04 4.208712E+00 1.461380E+02 4.246013E+04 4.173937E+00 1.464465E+02 4.230105E+04 4.161172E+00 1.467437E+02 4.162962E+04 4.162550E+00 1.470408E+02 4.153105E+04 4.208530E+00 1.473380E+02 4.158023E+04 4.225204E+00 1.476465E+02 4.117092E+04 4.181012E+00 1.479437E+02 4.071311E+04 4.157660E+00 1.482408E+02 4.061852E+04 4.206894E+00 1.485494E+02 4.045398E+04 4.170078E+00 1.488465E+02 4.026811E+04 4.212646E+00 1.491437E+02 3.977612E+04 4.212372E+00 1.494523E+02 3.951447E+04 4.152596E+00 1.497494E+02 3.964705E+04 4.223321E+00 1.500465E+02 3.931480E+04 4.264850E+00 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