********************* Core Excitation Data ******************** **************** A.P. Hitchcock & D.C. Mancini **************** * * Formula: Si(NtBuCH=CHNtBu) * Name: silylene * Edge: N 1s * Alpha Formula: C10H20N2Si * Data Source: Hitchcock * Filename: uo-0nnkk.os * Ref. Code: UH+98 * Write Date: 08/05/98 * Reference: Organometallics 17 (1998) 2352. * Source and Purity: Denk, sublimed under argon * Acquisition Mode: EELS, 2 deg, 2500eV CRE mode, 0.7eV fwhm *-------------------------------------------------------------- * No. of Spectra: 2 name1- 0uon1 name2- 0uon.os * E (eV) Raw data Osc. Str. per atom (E-2) *-------------------------------------------------------------- 3.908674E+02 2.038820E+04 -4.946125E-02 3.908999E+02 2.041000E+04 -4.713019E-02 3.910942E+02 2.021400E+04 -3.670835E-02 3.912999E+02 1.994100E+04 -4.722613E-02 3.914942E+02 2.003600E+04 -6.745021E-02 3.916999E+02 2.026700E+04 -5.800564E-02 3.918942E+02 2.000000E+04 -2.725733E-02 3.920999E+02 2.008500E+04 -7.784227E-03 3.922942E+02 2.010800E+04 -8.979640E-03 3.924999E+02 1.990500E+04 -1.081598E-02 3.926942E+02 2.001500E+04 3.418507E-03 3.928999E+02 1.978700E+04 1.846127E-02 3.930942E+02 1.983700E+04 4.015586E-02 3.932999E+02 1.978400E+04 7.820959E-02 3.934942E+02 1.958400E+04 8.825488E-02 3.936999E+02 1.956700E+04 4.099046E-02 3.938942E+02 1.969900E+04 -9.231869E-03 3.940999E+02 1.969000E+04 -2.311516E-02 3.942942E+02 1.969900E+04 2.760086E-04 3.944999E+02 1.952500E+04 4.413114E-02 3.946942E+02 1.964600E+04 3.597095E-02 3.949000E+02 1.959300E+04 1.028122E-02 3.950942E+02 1.959000E+04 5.116823E-02 3.952999E+02 1.971500E+04 7.048487E-02 3.954942E+02 1.981300E+04 2.559797E-02 3.956999E+02 1.958400E+04 2.310237E-02 3.958942E+02 1.923600E+04 4.020987E-02 3.960999E+02 1.931300E+04 2.429190E-02 3.962942E+02 1.910700E+04 2.023523E-02 3.964999E+02 1.950900E+04 2.694018E-02 3.966942E+02 1.939900E+04 1.362923E-02 3.969000E+02 1.903200E+04 -2.248664E-02 3.970942E+02 1.924300E+04 -3.099884E-02 3.972999E+02 1.955800E+04 7.364796E-03 3.974942E+02 1.897000E+04 2.194555E-02 3.976999E+02 1.903600E+04 -6.129016E-03 3.978942E+02 1.924500E+04 -1.229318E-02 3.980999E+02 1.889900E+04 -1.202899E-02 3.982942E+02 1.901300E+04 -4.200547E-02 3.985000E+02 1.889500E+04 -1.579935E-02 3.986942E+02 1.898900E+04 1.000878E-02 3.989000E+02 1.866900E+04 1.792932E-02 3.990942E+02 1.858300E+04 9.830687E-03 3.992999E+02 1.870400E+04 3.639841E-03 3.994942E+02 1.889600E+04 -2.085947E-02 3.996999E+02 1.853000E+04 -2.032382E-02 3.998942E+02 1.854100E+04 8.257054E-03 4.001000E+02 1.863700E+04 -1.988998E-02 4.002942E+02 1.836500E+04 -3.387081E-02 4.003987E+02 1.832000E+04 -1.351861E-02 4.005015E+02 1.840100E+04 2.380984E-02 4.005930E+02 1.857000E+04 6.668276E-02 4.006959E+02 1.838700E+04 7.540201E-02 4.007987E+02 1.859200E+04 5.785720E-02 4.009016E+02 1.845300E+04 4.830389E-02 4.009930E+02 1.848000E+04 4.716722E-02 4.010958E+02 1.842300E+04 4.735467E-02 4.011987E+02 1.839900E+04 4.107308E-02 4.013016E+02 1.849500E+04 2.844950E-02 4.013930E+02 1.831000E+04 2.776980E-02 4.014958E+02 1.815500E+04 4.418817E-02 4.015987E+02 1.851200E+04 8.575849E-02 4.017016E+02 1.826800E+04 1.388755E-01 4.017930E+02 1.826900E+04 1.804200E-01 4.018959E+02 1.856100E+04 2.467970E-01 4.019987E+02 1.852600E+04 3.189911E-01 4.021016E+02 1.869000E+04 3.684186E-01 4.021930E+02 1.859800E+04 4.119705E-01 4.022959E+02 1.892500E+04 4.735235E-01 4.023987E+02 1.940700E+04 5.466509E-01 4.025016E+02 1.973800E+04 6.207323E-01 4.025930E+02 2.068500E+04 6.945782E-01 4.026959E+02 2.136000E+04 7.590944E-01 4.027987E+02 2.205600E+04 8.106070E-01 4.029016E+02 2.273900E+04 8.915823E-01 4.029930E+02 2.331400E+04 9.540476E-01 4.030958E+02 2.360300E+04 9.705116E-01 4.031987E+02 2.357600E+04 9.651789E-01 4.033016E+02 2.311500E+04 9.299598E-01 4.033930E+02 2.251500E+04 8.675495E-01 4.034958E+02 2.191500E+04 8.126675E-01 4.035987E+02 2.099300E+04 7.691848E-01 4.037016E+02 2.079000E+04 7.119440E-01 4.037930E+02 2.003600E+04 6.642056E-01 4.038959E+02 1.983600E+04 6.297510E-01 4.039987E+02 1.975400E+04 6.205986E-01 4.041016E+02 1.951100E+04 6.422433E-01 4.041930E+02 1.951000E+04 6.753319E-01 4.042959E+02 1.943100E+04 7.226938E-01 4.043987E+02 1.966200E+04 7.768343E-01 4.045016E+02 1.973800E+04 8.425143E-01 4.045930E+02 1.985000E+04 9.044232E-01 4.046959E+02 2.025600E+04 9.405712E-01 4.047987E+02 2.006300E+04 9.708082E-01 4.049016E+02 2.039000E+04 1.021218E+00 4.049930E+02 2.070300E+04 1.078820E+00 4.050958E+02 2.067600E+04 1.143506E+00 4.051987E+02 2.060900E+04 1.175748E+00 4.053016E+02 2.067800E+04 1.188941E+00 4.053930E+02 2.031000E+04 1.236120E+00 4.054959E+02 2.008500E+04 1.312204E+00 4.055987E+02 2.005200E+04 1.348969E+00 4.057016E+02 1.979900E+04 1.314437E+00 4.057930E+02 1.958300E+04 1.290813E+00 4.058959E+02 1.953000E+04 1.316878E+00 4.059987E+02 1.927400E+04 1.330463E+00 4.061016E+02 1.950300E+04 1.328774E+00 4.061930E+02 1.943000E+04 1.349682E+00 4.062959E+02 1.964100E+04 1.381957E+00 4.063987E+02 1.976600E+04 1.394120E+00 4.065016E+02 1.986900E+04 1.394778E+00 4.065930E+02 2.015400E+04 1.409940E+00 4.066959E+02 2.033200E+04 1.412123E+00 4.067987E+02 2.013200E+04 1.389465E+00 4.069016E+02 2.055200E+04 1.377292E+00 4.069930E+02 2.039500E+04 1.388124E+00 4.070959E+02 2.087700E+04 1.403599E+00 4.071987E+02 2.090100E+04 1.404507E+00 4.073016E+02 2.086900E+04 1.389243E+00 4.073930E+02 2.087200E+04 1.363665E+00 4.074959E+02 2.125200E+04 1.362703E+00 4.075987E+02 2.142600E+04 1.404343E+00 4.077016E+02 2.144500E+04 1.438744E+00 4.077930E+02 2.089500E+04 1.443597E+00 4.078959E+02 2.134300E+04 1.450033E+00 4.079987E+02 2.131300E+04 1.464973E+00 4.081016E+02 2.122200E+04 1.452902E+00 4.081930E+02 2.132000E+04 1.411949E+00 4.082959E+02 2.139500E+04 1.373344E+00 4.083987E+02 2.159000E+04 1.355722E+00 4.085016E+02 2.134000E+04 1.344836E+00 4.085930E+02 2.149100E+04 1.325696E+00 4.086959E+02 2.158600E+04 1.303221E+00 4.087987E+02 2.137100E+04 1.295256E+00 4.089016E+02 2.141100E+04 1.291461E+00 4.089930E+02 2.131500E+04 1.275866E+00 4.090959E+02 2.159700E+04 1.235739E+00 4.091987E+02 2.142600E+04 1.191004E+00 4.093016E+02 2.155500E+04 1.164948E+00 4.093930E+02 2.133400E+04 1.171203E+00 4.094959E+02 2.114400E+04 1.188219E+00 4.095987E+02 2.130400E+04 1.165741E+00 4.097016E+02 2.142800E+04 1.145592E+00 4.097930E+02 2.137600E+04 1.148180E+00 4.098959E+02 2.128200E+04 1.140255E+00 4.099987E+02 2.140700E+04 1.131054E+00 4.101016E+02 2.143700E+04 1.134841E+00 4.101930E+02 2.129000E+04 1.147162E+00 4.102959E+02 2.108600E+04 1.138026E+00 4.103987E+02 2.112700E+04 1.131658E+00 4.105016E+02 2.102200E+04 1.150420E+00 4.105930E+02 2.112500E+04 1.140290E+00 4.106959E+02 2.082500E+04 1.142258E+00 4.107987E+02 2.094100E+04 1.190549E+00 4.109016E+02 2.081100E+04 1.198730E+00 4.109930E+02 2.085200E+04 1.177385E+00 4.110959E+02 2.074700E+04 1.180481E+00 4.111987E+02 2.041900E+04 1.182275E+00 4.113016E+02 2.052400E+04 1.172526E+00 4.113930E+02 2.017000E+04 1.162267E+00 4.114959E+02 2.066300E+04 1.156485E+00 4.115987E+02 2.040800E+04 1.156265E+00 4.117016E+02 2.016600E+04 1.148566E+00 4.117930E+02 2.043600E+04 1.139501E+00 4.118959E+02 2.016000E+04 1.144229E+00 4.119987E+02 2.030500E+04 1.163950E+00 4.121016E+02 2.010300E+04 1.163797E+00 4.121930E+02 2.024900E+04 1.143654E+00 4.122959E+02 2.035200E+04 1.133018E+00 4.123987E+02 1.990000E+04 1.146007E+00 4.125016E+02 2.034500E+04 1.158585E+00 4.125930E+02 2.019700E+04 1.151805E+00 4.126959E+02 1.993600E+04 1.144880E+00 4.127987E+02 2.025100E+04 1.142258E+00 4.129016E+02 2.049800E+04 1.124864E+00 4.129930E+02 1.997900E+04 1.109590E+00 4.130959E+02 2.029200E+04 1.116332E+00 4.131988E+02 2.013900E+04 1.122829E+00 4.133016E+02 2.014900E+04 1.101748E+00 4.133930E+02 2.012300E+04 1.082756E+00 4.134959E+02 1.996400E+04 1.088203E+00 4.135987E+02 2.011800E+04 1.082112E+00 4.137016E+02 1.991500E+04 1.051878E+00 4.137930E+02 2.003500E+04 1.034317E+00 4.138959E+02 1.979200E+04 1.039244E+00 4.139987E+02 2.005900E+04 1.049305E+00 4.141016E+02 2.000000E+04 1.039766E+00 4.141930E+02 1.991400E+04 1.035611E+00 4.142959E+02 1.981600E+04 1.048705E+00 4.143987E+02 1.980100E+04 1.062040E+00 4.145016E+02 1.999200E+04 1.071431E+00 4.145930E+02 1.983400E+04 1.073877E+00 4.146959E+02 1.985100E+04 1.072346E+00 4.147987E+02 1.979800E+04 1.058773E+00 4.149016E+02 1.987000E+04 1.048090E+00 4.149930E+02 1.958600E+04 1.042927E+00 4.150959E+02 1.974900E+04 1.038595E+00 4.151988E+02 1.972000E+04 1.038422E+00 4.153016E+02 1.978300E+04 1.036400E+00 4.153930E+02 1.948800E+04 1.031844E+00 4.154959E+02 1.961300E+04 1.026029E+00 4.155987E+02 1.973000E+04 1.018294E+00 4.157016E+02 1.943600E+04 1.013072E+00 4.157930E+02 1.952100E+04 1.012197E+00 4.158959E+02 1.928600E+04 1.013716E+00 4.159987E+02 1.962300E+04 1.022266E+00 4.161016E+02 1.937700E+04 1.026117E+00 4.161930E+02 1.941500E+04 1.022511E+00 4.162959E+02 1.939800E+04 1.017246E+00 4.164957E+02 1.949900E+04 1.002058E+00 4.167014E+02 1.953500E+04 9.905821E-01 4.168957E+02 1.932600E+04 9.568426E-01 4.171014E+02 1.930000E+04 9.191741E-01 4.172957E+02 1.931200E+04 9.082457E-01 4.175014E+02 1.919300E+04 9.229975E-01 4.176957E+02 1.917100E+04 9.368644E-01 4.179014E+02 1.902200E+04 9.130957E-01 4.180957E+02 1.917900E+04 8.490933E-01 4.183014E+02 1.905700E+04 8.098791E-01 4.184957E+02 1.888300E+04 8.165498E-01 4.187014E+02 1.901800E+04 8.261359E-01 4.188957E+02 1.872200E+04 8.229432E-01 4.191014E+02 1.867100E+04 7.993888E-01 4.192957E+02 1.846200E+04 7.721199E-01 4.195014E+02 1.865400E+04 7.706023E-01 4.196957E+02 1.855400E+04 7.662368E-01 4.199015E+02 1.871000E+04 7.706178E-01 4.200957E+02 1.824400E+04 7.995815E-01 4.203014E+02 1.811900E+04 7.663851E-01 4.204957E+02 1.816400E+04 6.872965E-01 4.207014E+02 1.818700E+04 6.602673E-01 4.208957E+02 1.816000E+04 6.975234E-01 4.211014E+02 1.810800E+04 7.183016E-01 4.212957E+02 1.788100E+04 6.885145E-01 4.215015E+02 1.788300E+04 6.773233E-01 4.216957E+02 1.796400E+04 6.985667E-01 4.219015E+02 1.759400E+04 6.992487E-01 4.220957E+02 1.807800E+04 6.763726E-01 4.223014E+02 1.781100E+04 6.579261E-01 4.224957E+02 1.744700E+04 6.475654E-01 4.227014E+02 1.723200E+04 6.483533E-01 4.228957E+02 1.740300E+04 6.406714E-01 4.231015E+02 1.762200E+04 6.324751E-01 4.232957E+02 1.725500E+04 6.494452E-01 4.235015E+02 1.723900E+04 6.430030E-01 4.236957E+02 1.728800E+04 5.957573E-01 4.239015E+02 1.736600E+04 5.546441E-01 4.240957E+02 1.709100E+04 5.465952E-01 4.243014E+02 1.714500E+04 5.730131E-01 4.244958E+02 1.694800E+04 6.102705E-01 4.247014E+02 1.699700E+04 6.102850E-01 4.248957E+02 1.697500E+04 5.860710E-01 4.251015E+02 1.674900E+04 5.907456E-01 4.252957E+02 1.694000E+04 6.009258E-01 4.255015E+02 1.691600E+04 5.781637E-01 4.256957E+02 1.667400E+04 5.597692E-01 4.259015E+02 1.646700E+04 5.634022E-01 4.260958E+02 1.643800E+04 5.659048E-01 4.263014E+02 1.640800E+04 5.767900E-01 4.264958E+02 1.665500E+04 5.939461E-01 4.267015E+02 1.661400E+04 6.043773E-01 4.268957E+02 1.639800E+04 6.010597E-01 4.271015E+02 1.638600E+04 5.810276E-01 4.272957E+02 1.653000E+04 5.607482E-01 4.275015E+02 1.632500E+04 5.482122E-01 4.276957E+02 1.618300E+04 5.540708E-01 4.279015E+02 1.626300E+04 5.553790E-01 4.280958E+02 1.617800E+04 5.326618E-01 4.283015E+02 1.617200E+04 5.368471E-01 4.284958E+02 1.626200E+04 5.700483E-01 4.287015E+02 1.618500E+04 5.714589E-01 4.288957E+02 1.628000E+04 5.488911E-01 4.291015E+02 1.603400E+04 5.459468E-01 4.292957E+02 1.606000E+04 5.437698E-01 4.295015E+02 1.588000E+04 5.079233E-01 4.296958E+02 1.591500E+04 4.912378E-01 4.299015E+02 1.597800E+04 5.125293E-01 4.300958E+02 1.577400E+04 5.090047E-01 4.303015E+02 1.567200E+04 5.048181E-01 4.304958E+02 1.592300E+04 5.304909E-01 4.307015E+02 1.587400E+04 5.398356E-01 4.308957E+02 1.570300E+04 5.240696E-01 4.311015E+02 1.567500E+04 5.188392E-01 4.312958E+02 1.574000E+04 5.170374E-01 4.315015E+02 1.557500E+04 5.182301E-01 4.316958E+02 1.526400E+04 5.193568E-01 4.319015E+02 1.563800E+04 5.278825E-01 4.320958E+02 1.541200E+04 5.395557E-01 4.323015E+02 1.534600E+04 5.494412E-01 4.324958E+02 1.544900E+04 5.462439E-01 4.327015E+02 1.553800E+04 5.428582E-01 4.328957E+02 1.533700E+04 5.322196E-01 4.331015E+02 1.533400E+04 5.174941E-01 4.332958E+02 1.536300E+04 5.058900E-01 4.337989E+02 1.513100E+04 5.067973E-01 4.343017E+02 1.537000E+04 5.243447E-01 4.347931E+02 1.522000E+04 5.442947E-01 4.352960E+02 1.491800E+04 5.414047E-01 4.357989E+02 1.496200E+04 5.113161E-01 4.363017E+02 1.490000E+04 5.148836E-01 4.367931E+02 1.492300E+04 5.444798E-01 4.372960E+02 1.493600E+04 5.435518E-01 4.377989E+02 1.461800E+04 4.989155E-01 4.383017E+02 1.459100E+04 4.605676E-01 4.387932E+02 1.472300E+04 4.927291E-01 4.392960E+02 1.461700E+04 5.519931E-01 4.397989E+02 1.447100E+04 5.677869E-01 4.403018E+02 1.406700E+04 5.641251E-01 4.407932E+02 1.424400E+04 5.486301E-01 4.412960E+02 1.440900E+04 5.237205E-01 4.417989E+02 1.441000E+04 5.213635E-01 4.423018E+02 1.421900E+04 5.073054E-01 4.427932E+02 1.432700E+04 4.892342E-01 4.432960E+02 1.386300E+04 5.083014E-01 4.437989E+02 1.409800E+04 5.340263E-01 4.443018E+02 1.382500E+04 5.352651E-01 4.447932E+02 1.373100E+04 5.098565E-01 4.452960E+02 1.369900E+04 4.909194E-01 4.457989E+02 1.384800E+04 5.181301E-01 4.463018E+02 1.368300E+04 5.579861E-01 4.467932E+02 1.366700E+04 5.406665E-01 4.472960E+02 1.331600E+04 4.747562E-01 4.477989E+02 1.353300E+04 4.648986E-01 4.483018E+02 1.353400E+04 5.116847E-01 4.487932E+02 1.361400E+04 5.156471E-01 4.492960E+02 1.305900E+04 4.782232E-01 4.497989E+02 1.301200E+04 4.639358E-01 4.503018E+02 1.326600E+04 4.834101E-01 4.507932E+02 1.317800E+04 5.000432E-01 4.512960E+02 1.293900E+04 4.963546E-01 4.517989E+02 1.280200E+04 4.785206E-01 4.523018E+02 1.289600E+04 4.672768E-01 4.527607E+02 1.286238E+04 4.686512E-01