********************* Core Excitation Data ******************** **************** A.P. Hitchcock & D.C. Mancini **************** * * Formula: Si(NtBuCH=CHNtBu) * Name: silylene * Edge: C 1s * Alpha Formula: C10H20N2Si * Data Source: Hitchcock * Filename: uo-0cckk.os * Ref. Code: UH+98 * Write Date: 08/05/98 * Reference: Organometallics 17 (1998) 2352. * Source and Purity: Denk, sublimed under argon * Acquisition Mode: EELS, 2 deg, 2500eV CRE mode, 0.7eV fwhm *-------------------------------------------------------------- * No. of Spectra: 2 name1- 0uoc13 name2- 0uoc.os * E (eV) Raw data Osc. Str. per atom (E-2) *-------------------------------------------------------------- 2.698490E+02 1.440983E+04 -2.969728E-03 2.700367E+02 1.451700E+04 5.452308E-04 2.702424E+02 1.454100E+04 2.077792E-03 2.704366E+02 1.460200E+04 4.404527E-03 2.706424E+02 1.423800E+04 -3.771242E-03 2.708366E+02 1.436400E+04 -1.528253E-04 2.710424E+02 1.430300E+04 -7.317517E-04 2.712366E+02 1.420200E+04 -2.517604E-03 2.714424E+02 1.434300E+04 1.748605E-03 2.716367E+02 1.431300E+04 1.899045E-03 2.718423E+02 1.419900E+04 -1.570256E-04 2.720367E+02 1.414100E+04 -9.275033E-04 2.722424E+02 1.424100E+04 2.357553E-03 2.724366E+02 1.422200E+04 2.742126E-03 2.726424E+02 1.408400E+04 7.249631E-05 2.728366E+02 1.379200E+04 -6.615442E-03 2.730424E+02 1.422100E+04 4.762393E-03 2.732366E+02 1.406100E+04 1.864025E-03 2.734424E+02 1.387300E+04 -2.219436E-03 2.736367E+02 1.389400E+04 -1.080673E-03 2.738423E+02 1.410400E+04 5.069535E-03 2.740367E+02 1.403900E+04 4.373340E-03 2.742424E+02 1.390900E+04 1.825585E-03 2.744366E+02 1.395600E+04 3.672738E-03 2.746424E+02 1.387500E+04 2.462644E-03 2.748366E+02 1.381800E+04 1.706562E-03 2.750424E+02 1.352300E+04 -5.067723E-03 2.752366E+02 1.360300E+04 -2.527970E-03 2.754424E+02 1.351400E+04 -3.934081E-03 2.756367E+02 1.348000E+04 -4.128111E-03 2.758423E+02 1.370700E+04 2.448062E-03 2.760367E+02 1.337600E+04 -5.077550E-03 2.762424E+02 1.334900E+04 -5.280093E-03 2.764366E+02 1.336100E+04 -4.252364E-03 2.766424E+02 1.366300E+04 4.319664E-03 2.768366E+02 1.350000E+04 1.137187E-03 2.770424E+02 1.350500E+04 1.906994E-03 2.772366E+02 1.328700E+04 -2.959464E-03 2.774424E+02 1.322900E+04 -3.876081E-03 2.776367E+02 1.361600E+04 6.805197E-03 2.778423E+02 1.314200E+04 -4.324767E-03 2.780367E+02 1.333800E+04 1.068677E-03 2.782424E+02 1.320300E+04 -1.476741E-03 2.784366E+02 1.306800E+04 -4.359266E-03 2.786424E+02 1.318900E+04 -5.626425E-04 2.788366E+02 1.298100E+04 -5.130741E-03 2.790424E+02 1.315700E+04 3.444711E-05 2.792366E+02 1.315600E+04 8.911662E-04 2.794424E+02 1.313200E+04 1.036450E-03 2.796367E+02 1.291000E+04 -4.050040E-03 2.798423E+02 1.306400E+04 5.399634E-04 2.800367E+02 1.318300E+04 4.515481E-03 2.802424E+02 1.307600E+04 2.588567E-03 2.804366E+02 1.290800E+04 -1.181711E-03 2.806424E+02 1.307300E+04 3.763350E-03 2.808366E+02 1.382900E+04 4.438939E-03 2.810424E+02 1.305800E+04 4.995554E-03 2.812366E+02 1.297600E+04 3.553442E-03 2.814424E+02 1.284600E+04 8.062430E-04 2.816367E+02 1.282800E+04 9.336690E-04 2.818423E+02 1.268600E+04 -2.082223E-03 2.820367E+02 1.268700E+04 -1.471471E-03 2.822424E+02 1.262200E+04 -2.442677E-03 2.824366E+02 1.257300E+04 -3.090142E-03 2.826424E+02 1.254700E+04 -3.079717E-03 2.828366E+02 1.259900E+04 -1.018426E-03 2.829377E+02 1.277300E+04 3.870442E-03 2.830405E+02 1.250400E+04 -2.368075E-03 2.831319E+02 1.280400E+04 5.139999E-03 2.832348E+02 1.266800E+04 2.616725E-03 2.833376E+02 1.275000E+04 4.862476E-03 2.834405E+02 1.268600E+04 3.735576E-03 2.835320E+02 1.284100E+04 7.920779E-03 2.836348E+02 1.273600E+04 5.893067E-03 2.837376E+02 1.276000E+04 6.701245E-03 2.838405E+02 1.308700E+04 1.556727E-02 2.839319E+02 1.323900E+04 2.038409E-02 2.840348E+02 1.355600E+04 2.927741E-02 2.841377E+02 1.407100E+04 4.356668E-02 2.842405E+02 1.495900E+04 6.786279E-02 2.843319E+02 1.621300E+04 1.020176E-01 2.844348E+02 1.745600E+04 1.372246E-01 2.845377E+02 1.926300E+04 1.867614E-01 2.846405E+02 2.073200E+04 2.286002E-01 2.847319E+02 2.215100E+04 2.681634E-01 2.848348E+02 2.307900E+04 2.956540E-01 2.849377E+02 2.364700E+04 3.126274E-01 2.850405E+02 2.353800E+04 3.113387E-01 2.851319E+02 2.344500E+04 3.092217E-01 2.852348E+02 2.258500E+04 2.871651E-01 2.853376E+02 2.209700E+04 2.734473E-01 2.854405E+02 2.199400E+04 2.703914E-01 2.855320E+02 2.232600E+04 2.792464E-01 2.856348E+02 2.354100E+04 3.121431E-01 2.857376E+02 2.547500E+04 3.653131E-01 2.858405E+02 2.831700E+04 4.435761E-01 2.859319E+02 3.078600E+04 5.131675E-01 2.860348E+02 3.480900E+04 6.240703E-01 2.861377E+02 3.879900E+04 7.364385E-01 2.862405E+02 4.026200E+04 7.826206E-01 2.863319E+02 4.202400E+04 8.316909E-01 2.864348E+02 4.381700E+04 8.831045E-01 2.865377E+02 4.488700E+04 9.152144E-01 2.866405E+02 4.612800E+04 9.505598E-01 2.867319E+02 4.654900E+04 9.645116E-01 2.868348E+02 4.699100E+04 9.778522E-01 2.869377E+02 4.756700E+04 9.946811E-01 2.870405E+02 4.820800E+04 1.013466E+00 2.871319E+02 4.934300E+04 1.044986E+00 2.872348E+02 5.071300E+04 1.084307E+00 2.873376E+02 5.321900E+04 1.153633E+00 2.874405E+02 5.638900E+04 1.242636E+00 2.875320E+02 5.956100E+04 1.332274E+00 2.876348E+02 6.208200E+04 1.406282E+00 2.877376E+02 6.450000E+04 1.475701E+00 2.878405E+02 6.571100E+04 1.513222E+00 2.879319E+02 6.661000E+04 1.539989E+00 2.880348E+02 6.636000E+04 1.536429E+00 2.881377E+02 6.537700E+04 1.511156E+00 2.882405E+02 6.423500E+04 1.480349E+00 2.883319E+02 6.270000E+04 1.439030E+00 2.884348E+02 6.130700E+04 1.400086E+00 2.885377E+02 5.990900E+04 1.361624E+00 2.886405E+02 5.881700E+04 1.331206E+00 2.887319E+02 5.780700E+04 1.303632E+00 2.888348E+02 5.764700E+04 1.298348E+00 2.889377E+02 5.773700E+04 1.301491E+00 2.890405E+02 5.832800E+04 1.318404E+00 2.891319E+02 5.937100E+04 1.347867E+00 2.892348E+02 6.018300E+04 1.372708E+00 2.893376E+02 6.178000E+04 1.417715E+00 2.894405E+02 6.250800E+04 1.441143E+00 2.895320E+02 6.339400E+04 1.466889E+00 2.896348E+02 6.394800E+04 1.484605E+00 2.897376E+02 6.410000E+04 1.490806E+00 2.898405E+02 6.474300E+04 1.509370E+00 2.899319E+02 6.483200E+04 1.513938E+00 2.900348E+02 6.588700E+04 1.543446E+00 2.901377E+02 6.598700E+04 1.549228E+00 2.902405E+02 6.621900E+04 1.556779E+00 2.903319E+02 6.674400E+04 1.572162E+00 2.904348E+02 6.742000E+04 1.592535E+00 2.905377E+02 6.776100E+04 1.604096E+00 2.906405E+02 6.785500E+04 1.608443E+00 2.907319E+02 6.829100E+04 1.621256E+00 2.908348E+02 6.830400E+04 1.623724E+00 2.909377E+02 6.860400E+04 1.633007E+00 2.910405E+02 6.914200E+04 1.649213E+00 2.911319E+02 6.970700E+04 1.666311E+00 2.912348E+02 7.010100E+04 1.679320E+00 2.913376E+02 7.024700E+04 1.685200E+00 2.914405E+02 7.018500E+04 1.685046E+00 2.915320E+02 7.088500E+04 1.704709E+00 2.916348E+02 7.175100E+04 1.730726E+00 2.917376E+02 7.150100E+04 1.726854E+00 2.918405E+02 7.168800E+04 1.732682E+00 2.919319E+02 7.193100E+04 1.740639E+00 2.920348E+02 7.237100E+04 1.754287E+00 2.921377E+02 7.284100E+04 1.769065E+00 2.922405E+02 7.284000E+04 1.771184E+00 2.923319E+02 7.265100E+04 1.767261E+00 2.924348E+02 7.320400E+04 1.783090E+00 2.925377E+02 7.355000E+04 1.794756E+00 2.926405E+02 7.272700E+04 1.774415E+00 2.927319E+02 7.352900E+04 1.795533E+00 2.928348E+02 7.395500E+04 1.810048E+00 2.929377E+02 7.366700E+04 1.804340E+00 2.930405E+02 7.305400E+04 1.788472E+00 2.931319E+02 7.346500E+04 1.799514E+00 2.932348E+02 7.333500E+04 1.798150E+00 2.933376E+02 7.309400E+04 1.792655E+00 2.934405E+02 7.252300E+04 1.777985E+00 2.935320E+02 7.233600E+04 1.772998E+00 2.936348E+02 7.262700E+04 1.781795E+00 2.937376E+02 7.186600E+04 1.762918E+00 2.938405E+02 7.147200E+04 1.752027E+00 2.939319E+02 7.131600E+04 1.748194E+00 2.940348E+02 7.201100E+04 1.768058E+00 2.941377E+02 7.099400E+04 1.742893E+00 2.942405E+02 7.086300E+04 1.738675E+00 2.943319E+02 7.004500E+04 1.717422E+00 2.944348E+02 6.972600E+04 1.708203E+00 2.945377E+02 6.918300E+04 1.694004E+00 2.946405E+02 6.879800E+04 1.683683E+00 2.947319E+02 6.861300E+04 1.679032E+00 2.948348E+02 6.768700E+04 1.654532E+00 2.950373E+02 6.755500E+04 1.651406E+00 2.952430E+02 6.636100E+04 1.619825E+00 2.954373E+02 6.592400E+04 1.608547E+00 2.956430E+02 6.528200E+04 1.592216E+00 2.958373E+02 6.398000E+04 1.556853E+00 2.960431E+02 6.317800E+04 1.534992E+00 2.962373E+02 6.288900E+04 1.528155E+00 2.964431E+02 6.231500E+04 1.513742E+00 2.966373E+02 6.166400E+04 1.496768E+00 2.968430E+02 6.152300E+04 1.494298E+00 2.970373E+02 6.059500E+04 1.469762E+00 2.972430E+02 6.000200E+04 1.454020E+00 2.974373E+02 5.957800E+04 1.443372E+00 2.976430E+02 5.918400E+04 1.433791E+00 2.978373E+02 5.902600E+04 1.430911E+00 2.980431E+02 5.811800E+04 1.406772E+00 2.982373E+02 5.831600E+04 1.413591E+00 2.984431E+02 5.768300E+04 1.397666E+00 2.986373E+02 5.746000E+04 1.392629E+00 2.988430E+02 5.754000E+04 1.396805E+00 2.990373E+02 5.711400E+04 1.386578E+00 2.992430E+02 5.650700E+04 1.370664E+00 2.994373E+02 5.634500E+04 1.367345E+00 2.996430E+02 5.615200E+04 1.363645E+00 2.998373E+02 5.577000E+04 1.354336E+00 3.000431E+02 5.599900E+04 1.362642E+00 3.002373E+02 5.494400E+04 1.334185E+00 3.004431E+02 5.490100E+04 1.333864E+00 3.006373E+02 5.495000E+04 1.337152E+00 3.008430E+02 5.442200E+04 1.323827E+00 3.010373E+02 5.430200E+04 1.321705E+00 3.012430E+02 5.362300E+04 1.303737E+00 3.014373E+02 5.330000E+04 1.295514E+00 3.016430E+02 5.309400E+04 1.291115E+00 3.018373E+02 5.267100E+04 1.280392E+00 3.020431E+02 5.272200E+04 1.283400E+00 3.022373E+02 5.230100E+04 1.272953E+00 3.024431E+02 5.226200E+04 1.273307E+00 3.026373E+02 5.095100E+04 1.236601E+00 3.028430E+02 5.073400E+04 1.230732E+00 3.030373E+02 5.072100E+04 1.231920E+00 3.032430E+02 5.017300E+04 1.217623E+00 3.034373E+02 4.964600E+04 1.203313E+00 3.036430E+02 4.962000E+04 1.203846E+00 3.038373E+02 4.951500E+04 1.202472E+00 3.040431E+02 4.857100E+04 1.176233E+00 3.042373E+02 4.857500E+04 1.177144E+00 3.044431E+02 4.816600E+04 1.166825E+00 3.046373E+02 4.786000E+04 1.159058E+00 3.048430E+02 4.759900E+04 1.152772E+00 3.050373E+02 4.684500E+04 1.131799E+00 3.052430E+02 4.614600E+04 1.111932E+00 3.054373E+02 4.611600E+04 1.111992E+00 3.056430E+02 4.603900E+04 1.111408E+00 3.058373E+02 4.564600E+04 1.101254E+00 3.060431E+02 4.520900E+04 1.089489E+00 3.062373E+02 4.445600E+04 1.068165E+00 3.064431E+02 4.444800E+04 1.068822E+00 3.066373E+02 4.409300E+04 1.059782E+00 3.068430E+02 4.375500E+04 1.050934E+00 3.070373E+02 4.352600E+04 1.045301E+00 3.072430E+02 4.296600E+04 1.029865E+00 3.074373E+02 4.275600E+04 1.024543E+00 3.076430E+02 4.255100E+04 1.019777E+00 3.078373E+02 4.236100E+04 1.015392E+00 3.080431E+02 4.224000E+04 1.013161E+00 3.082373E+02 4.173200E+04 9.992388E-01 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