********************* Core Excitation Data ******************** **************** A.P. Hitchcock & D.C. Mancini **************** * * Formula: Mn(CO)5Br * Name: Manganese carbonylbromide * Edge: O 1s * Alpha Formula: BrC5MnO5 * Data Source: Hitchcock * Filename: mb-0ookk.os * Ref. Code: RH89 * Write Date: 93/06/16 * Reference: J.Am.Chem.Soc. 111 (89) 5069. * Source and Purity: AT&T/Strem * Acquisition Mode: EELS, 2 deg., 2500 eV CRE, 0.7 eV fwhm *-------------------------------------------------------------- * No. of Spectra: 2 name1- 0mbo.add name2- 0mbo.os * E (eV) Raw data Osc. Str. per atom (E-2) *-------------------------------------------------------------- 5.222910E+02 2.599492E+03 -2.313823E-02 5.223740E+02 2.606770E+03 -2.455636E-02 5.225330E+02 2.584750E+03 -1.218113E-02 5.226920E+02 2.624700E+03 2.532279E-02 5.228510E+02 2.666990E+03 -1.531590E-02 5.230100E+02 2.545890E+03 -2.102800E-02 5.231690E+02 2.517000E+03 -1.351571E-03 5.233280E+02 2.516410E+03 8.294010E-04 5.234870E+02 2.598930E+03 -2.062754E-02 5.236460E+02 2.469610E+03 -1.871853E-02 5.238050E+02 2.442720E+03 -1.481714E-02 5.239640E+02 2.597220E+03 -1.487361E-02 5.241230E+02 2.558410E+03 -2.259265E-02 5.242810E+02 2.610640E+03 -2.631153E-02 5.244410E+02 2.563700E+03 -2.035405E-02 5.245990E+02 2.601060E+03 -2.351232E-02 5.247590E+02 2.600900E+03 -3.783253E-03 5.249170E+02 2.556010E+03 -4.307575E-03 5.250770E+02 2.559420E+03 -9.950829E-03 5.252350E+02 2.628810E+03 -1.011813E-02 5.253950E+02 2.524690E+03 -3.519985E-03 5.255530E+02 2.481320E+03 -1.074471E-02 5.257130E+02 2.548730E+03 -1.048358E-02 5.258710E+02 2.552510E+03 -5.903118E-03 5.260310E+02 2.549420E+03 -8.973549E-03 5.261890E+02 2.615040E+03 -1.505851E-02 5.263490E+02 2.548890E+03 -6.503661E-03 5.265070E+02 2.539940E+03 1.120418E-02 5.266670E+02 2.606110E+03 1.307590E-02 5.268250E+02 2.561890E+03 3.996094E-04 5.269840E+02 2.626620E+03 -1.500148E-02 5.271430E+02 2.482980E+03 -2.123030E-02 5.273020E+02 2.494420E+03 -1.264517E-02 5.274610E+02 2.500940E+03 -2.428348E-02 5.276200E+02 2.528930E+03 -1.604801E-02 5.277790E+02 2.534880E+03 -1.602170E-02 5.279380E+02 2.571850E+03 -8.153427E-03 5.280970E+02 2.631920E+03 1.654935E-02 5.282560E+02 2.581760E+03 6.456810E-03 5.284150E+02 2.506870E+03 -9.830744E-03 5.285740E+02 2.521180E+03 -3.086138E-03 5.287330E+02 2.539140E+03 -1.010174E-02 5.288920E+02 2.574400E+03 -2.188777E-02 5.290510E+02 2.509200E+03 -1.101955E-02 5.292100E+02 2.519650E+03 -1.403682E-02 5.293690E+02 2.573840E+03 -2.119394E-02 5.295280E+02 2.597640E+03 -1.763929E-02 5.296870E+02 2.448940E+03 2.557944E-03 5.298460E+02 2.411230E+03 1.882989E-02 5.300050E+02 2.622510E+03 -6.011214E-03 5.301640E+02 2.598520E+03 -2.592863E-02 5.303230E+02 2.661710E+03 -2.305713E-02 5.304820E+02 2.841860E+03 -2.510055E-02 5.306410E+02 2.824970E+03 -2.610975E-02 5.308000E+02 2.896710E+03 -2.715679E-03 5.309590E+02 2.874790E+03 7.777114E-02 5.311180E+02 2.793530E+03 4.001240E-02 5.312770E+02 2.690440E+03 2.643016E-02 5.314360E+02 2.628000E+03 2.428290E-02 5.315950E+02 2.593200E+03 2.750944E-02 5.317540E+02 2.640820E+03 3.603114E-02 5.319130E+02 2.524210E+03 5.848711E-02 5.320720E+02 2.600140E+03 9.966276E-02 5.322310E+02 2.751940E+03 1.537983E-01 5.323900E+02 2.735290E+03 2.265006E-01 5.325490E+02 2.999420E+03 3.616028E-01 5.327080E+02 3.115010E+03 6.119685E-01 5.328670E+02 3.570810E+03 9.622492E-01 5.330260E+02 4.351960E+03 1.354440E+00 5.331850E+02 5.152420E+03 1.895021E+00 5.333440E+02 6.239760E+03 2.421853E+00 5.335030E+02 7.099250E+03 2.823391E+00 5.336620E+02 7.712110E+03 3.095744E+00 5.338210E+02 7.818540E+03 3.142939E+00 5.339800E+02 7.541330E+03 3.175602E+00 5.341390E+02 7.059550E+03 3.013471E+00 5.342980E+02 6.289520E+03 2.693981E+00 5.344570E+02 5.526070E+03 2.317931E+00 5.346160E+02 4.837830E+03 1.964191E+00 5.347750E+02 4.297210E+03 1.592592E+00 5.349340E+02 3.801640E+03 1.272554E+00 5.350930E+02 3.494460E+03 1.016668E+00 5.352520E+02 3.243410E+03 8.214977E-01 5.354110E+02 3.090620E+03 6.787475E-01 5.355700E+02 3.022560E+03 5.919566E-01 5.357290E+02 3.010520E+03 5.470852E-01 5.358880E+02 2.905850E+03 4.717566E-01 5.360470E+02 2.801900E+03 4.183968E-01 5.362060E+02 2.827700E+03 3.839994E-01 5.363650E+02 2.777500E+03 3.292673E-01 5.365240E+02 2.786010E+03 3.075611E-01 5.366830E+02 2.695550E+03 3.119781E-01 5.368420E+02 2.906030E+03 2.888237E-01 5.370010E+02 2.721710E+03 2.589894E-01 5.371600E+02 2.794600E+03 2.576207E-01 5.373190E+02 2.753840E+03 3.073491E-01 5.374780E+02 2.713010E+03 2.505484E-01 5.376370E+02 2.713060E+03 2.333173E-01 5.377960E+02 2.861720E+03 2.163790E-01 5.379550E+02 2.786380E+03 2.105150E-01 5.381140E+02 2.734150E+03 2.242206E-01 5.382730E+02 2.746070E+03 2.292496E-01 5.384320E+02 2.742000E+03 2.400639E-01 5.385910E+02 2.877630E+03 2.327875E-01 5.387500E+02 2.758890E+03 2.220527E-01 5.389090E+02 2.798790E+03 2.285480E-01 5.390680E+02 2.825860E+03 2.563105E-01 5.392270E+02 2.796700E+03 2.427050E-01 5.393860E+02 2.831480E+03 2.194500E-01 5.395450E+02 2.832220E+03 2.409027E-01 5.397040E+02 2.947860E+03 2.518146E-01 5.398630E+02 2.803520E+03 2.385133E-01 5.400220E+02 2.873790E+03 2.313354E-01 5.401810E+02 2.787610E+03 2.495708E-01 5.403400E+02 2.850550E+03 2.438943E-01 5.404990E+02 2.886560E+03 2.476755E-01 5.406580E+02 2.827010E+03 2.685918E-01 5.408170E+02 2.832620E+03 2.867283E-01 5.409760E+02 2.871320E+03 2.586899E-01 5.411350E+02 2.903740E+03 2.422359E-01 5.412940E+02 2.870870E+03 2.896834E-01 5.414530E+02 2.967880E+03 2.888750E-01 5.416120E+02 2.931240E+03 2.811527E-01 5.417710E+02 2.901080E+03 3.122661E-01 5.419300E+02 2.922670E+03 3.101713E-01 5.420890E+02 2.881360E+03 2.588073E-01 5.422480E+02 2.803520E+03 2.973605E-01 5.424070E+02 2.891420E+03 3.181666E-01 5.425660E+02 2.949950E+03 3.237008E-01 5.427250E+02 2.898530E+03 3.556578E-01 5.428840E+02 2.874030E+03 3.271706E-01 5.430430E+02 2.895230E+03 3.334912E-01 5.432020E+02 2.983470E+03 3.483713E-01 5.433610E+02 2.917610E+03 3.430301E-01 5.435200E+02 2.967890E+03 3.285849E-01 5.436790E+02 2.973760E+03 3.462899E-01 5.438380E+02 2.979770E+03 3.749608E-01 5.439970E+02 2.808520E+03 3.629555E-01 5.441560E+02 2.872830E+03 3.759299E-01 5.443150E+02 2.953250E+03 3.973461E-01 5.444740E+02 2.936990E+03 4.027526E-01 5.446330E+02 3.033300E+03 3.881349E-01 5.447920E+02 3.104940E+03 4.105752E-01 5.449510E+02 3.010240E+03 4.130855E-01 5.451100E+02 3.092340E+03 4.404175E-01 5.452690E+02 3.076900E+03 4.675002E-01 5.454280E+02 3.103470E+03 4.718516E-01 5.455870E+02 3.058540E+03 5.072125E-01 5.457460E+02 3.047360E+03 4.801172E-01 5.459050E+02 3.143960E+03 4.901829E-01 5.460640E+02 3.079180E+03 5.197229E-01 5.462230E+02 3.163900E+03 5.316729E-01 5.463820E+02 3.297090E+03 5.069063E-01 5.465410E+02 3.187770E+03 5.445174E-01 5.467000E+02 3.181780E+03 5.598302E-01 5.468590E+02 3.144710E+03 5.635629E-01 5.470180E+02 3.287150E+03 5.552826E-01 5.471770E+02 3.272050E+03 5.596253E-01 5.473360E+02 3.210550E+03 6.138654E-01 5.474950E+02 3.201070E+03 6.261149E-01 5.476540E+02 3.275430E+03 6.152274E-01 5.478130E+02 3.218750E+03 6.055251E-01 5.479720E+02 3.330890E+03 6.195487E-01 5.481310E+02 3.356880E+03 6.543116E-01 5.482900E+02 3.388850E+03 6.690325E-01 5.484490E+02 3.298250E+03 7.116825E-01 5.486080E+02 3.493890E+03 7.187069E-01 5.487670E+02 3.347840E+03 7.259637E-01 5.489260E+02 3.435980E+03 7.290074E-01 5.490850E+02 3.355790E+03 7.195575E-01 5.492440E+02 3.454110E+03 7.300752E-01 5.494030E+02 3.454220E+03 7.952667E-01 5.495620E+02 3.466370E+03 7.750363E-01 5.497210E+02 3.485730E+03 7.525292E-01 5.498800E+02 3.435090E+03 7.673593E-01 5.500390E+02 3.361050E+03 8.028882E-01 5.501980E+02 3.392600E+03 7.700309E-01 5.503570E+02 3.436880E+03 7.421970E-01 5.505160E+02 3.419640E+03 7.492124E-01 5.506750E+02 3.338180E+03 7.524117E-01 5.508340E+02 3.312050E+03 7.363910E-01 5.509930E+02 3.379410E+03 7.206135E-01 5.511520E+02 3.321360E+03 6.622353E-01 5.513110E+02 3.369020E+03 6.677055E-01 5.514700E+02 3.459490E+03 6.668296E-01 5.516290E+02 3.362100E+03 6.694515E-01 5.517880E+02 3.272700E+03 6.764182E-01 5.519470E+02 3.339290E+03 6.324895E-01 5.521060E+02 3.201410E+03 6.528581E-01 5.522650E+02 3.271460E+03 6.100718E-01 5.524240E+02 3.334820E+03 6.043986E-01 5.525830E+02 3.229300E+03 6.418720E-01 5.527420E+02 3.169050E+03 6.719121E-01 5.529010E+02 3.144090E+03 6.158427E-01 5.530600E+02 3.223420E+03 6.163962E-01 5.532190E+02 3.259840E+03 5.901064E-01 5.533780E+02 3.284360E+03 5.794508E-01 5.535370E+02 3.181820E+03 5.818862E-01 5.536960E+02 3.134800E+03 5.622309E-01 5.538550E+02 3.337780E+03 5.482152E-01 5.540140E+02 3.149240E+03 5.463738E-01 5.541730E+02 3.123800E+03 5.515475E-01 5.543320E+02 3.048440E+03 5.531774E-01 5.544910E+02 3.106030E+03 5.429673E-01 5.546500E+02 3.130650E+03 5.195540E-01 5.548090E+02 3.139020E+03 5.185294E-01 5.549680E+02 3.226150E+03 5.204353E-01 5.551270E+02 3.129910E+03 5.372694E-01 5.552860E+02 3.047120E+03 5.449505E-01 5.554450E+02 3.056540E+03 5.330499E-01 5.556040E+02 3.001960E+03 5.410285E-01 5.557630E+02 3.109580E+03 5.555070E-01 5.559220E+02 3.111460E+03 5.547454E-01 5.560810E+02 3.162540E+03 5.288407E-01 5.562400E+02 3.106920E+03 4.941015E-01 5.563990E+02 3.078230E+03 4.803557E-01 5.565580E+02 2.976930E+03 5.169809E-01 5.567170E+02 3.053100E+03 5.026750E-01 5.568760E+02 3.069360E+03 4.705772E-01 5.570350E+02 3.130780E+03 4.579047E-01 5.571940E+02 3.081570E+03 4.659578E-01 5.573530E+02 3.006860E+03 4.685301E-01 5.575120E+02 3.099130E+03 4.748679E-01 5.576710E+02 3.040740E+03 4.951838E-01 5.578300E+02 3.085890E+03 4.681377E-01 5.579890E+02 2.990400E+03 4.396409E-01 5.581480E+02 3.069310E+03 4.432073E-01 5.583070E+02 2.983160E+03 4.630186E-01 5.584660E+02 3.044330E+03 4.751670E-01 5.586250E+02 2.979670E+03 4.890002E-01 5.587840E+02 3.088320E+03 4.827584E-01 5.589430E+02 2.991880E+03 4.681161E-01 5.591020E+02 2.994750E+03 4.653090E-01 5.592610E+02 3.054980E+03 4.849160E-01 5.594200E+02 3.044020E+03 4.412278E-01 5.595790E+02 3.131430E+03 4.688853E-01 5.597380E+02 3.045470E+03 4.566682E-01 5.598970E+02 3.048060E+03 4.291564E-01 5.600560E+02 2.987690E+03 4.542150E-01 5.602150E+02 2.963610E+03 4.307858E-01 5.603740E+02 3.018500E+03 4.325746E-01 5.605330E+02 2.996150E+03 4.323612E-01 5.606920E+02 3.008640E+03 4.589303E-01 5.608510E+02 2.978830E+03 4.998886E-01 5.610100E+02 3.087960E+03 5.058058E-01 5.611690E+02 2.988430E+03 4.828454E-01 5.613280E+02 2.996690E+03 4.910019E-01 5.614870E+02 2.987560E+03 4.787216E-01 5.616460E+02 3.001840E+03 4.509928E-01 5.618050E+02 3.003940E+03 4.427517E-01 5.619640E+02 3.002630E+03 5.059810E-01 5.621230E+02 2.980860E+03 5.284805E-01 5.622820E+02 2.938770E+03 5.079633E-01 5.624410E+02 2.950980E+03 4.779738E-01 5.626000E+02 2.938050E+03 4.412883E-01 5.627590E+02 3.039500E+03 4.072933E-01 5.629180E+02 3.006840E+03 4.316807E-01 5.630770E+02 2.978880E+03 4.814257E-01 5.632360E+02 2.966810E+03 4.534135E-01 5.633950E+02 2.977010E+03 4.575303E-01 5.635540E+02 2.992050E+03 4.894832E-01 5.637130E+02 3.067240E+03 4.800578E-01 5.638720E+02 3.029380E+03 4.405554E-01 5.640310E+02 2.950480E+03 4.818663E-01 5.641900E+02 2.922640E+03 4.860726E-01 5.643490E+02 3.065580E+03 4.756321E-01 5.645080E+02 3.033350E+03 4.710293E-01 5.646670E+02 2.968480E+03 4.730769E-01 5.648260E+02 3.066140E+03 5.051739E-01 5.649850E+02 2.982310E+03 4.578276E-01 5.651440E+02 2.964480E+03 4.601524E-01 5.653030E+02 2.989150E+03 4.557644E-01 5.654620E+02 2.974380E+03 4.247502E-01 5.656210E+02 2.988290E+03 4.783126E-01 5.657800E+02 2.837470E+03 4.613422E-01 5.659390E+02 2.902310E+03 4.452083E-01 5.660980E+02 2.885850E+03 4.592886E-01 5.662570E+02 2.904460E+03 4.491907E-01 5.664160E+02 2.997250E+03 3.893232E-01 5.665750E+02 2.942540E+03 4.385304E-01 5.667340E+02 2.941710E+03 4.411308E-01 5.668930E+02 3.032020E+03 4.243674E-01 5.670520E+02 3.028110E+03 4.545771E-01 5.672110E+02 2.981830E+03 4.872015E-01 5.673700E+02 2.923890E+03 4.396652E-01 5.675290E+02 2.884300E+03 4.484998E-01 5.676880E+02 2.872540E+03 4.553366E-01 5.678470E+02 2.884760E+03 4.325318E-01 5.680060E+02 2.891160E+03 4.209192E-01 5.681650E+02 2.963680E+03 4.360747E-01 5.683240E+02 2.903510E+03 4.504168E-01 5.684830E+02 2.973780E+03 4.177972E-01 5.686420E+02 2.910150E+03 4.423790E-01 5.688010E+02 2.910730E+03 4.648032E-01 5.689600E+02 2.922700E+03 4.701125E-01 5.691190E+02 2.856920E+03 4.631777E-01 5.692780E+02 3.032240E+03 4.612685E-01 5.694370E+02 2.963390E+03 4.126526E-01 5.695960E+02 3.018200E+03 4.283182E-01 5.696620E+02 2.983824E+03 4.417945E-01