********************* Core Excitation Data ******************** **************** A.P. Hitchcock & D.C. Mancini **************** * * Formula: Fe2(CO)9 * Name: Iron nonacarbonyl * Edge: O 1s * Alpha Formula: C9Fe2O9 * Data Source: Hitchcock * Filename: fk-0ookk.os * Ref. Code: WRH92 * Write Date: 93/06/10 * Reference: Organometallics 11 (92) 2559. * Source and Purity: Strem * Acquisition Mode: EELS, 2 deg, 2500 eV CRE mode, 0.7 eV fwhm *-------------------------------------------------------------- * No. of Spectra: 2 name1- 0fko. name2- 0fko-ox name3- 0fko-ox.os * E (eV) Raw data Osc. Str. per atom (E-2) *-------------------------------------------------------------- 5.191900E+02 5.890000E+02 6.030940E+02 -1.200689E-02 5.193088E+02 6.060000E+02 6.250039E+02 2.117458E-02 5.194276E+02 6.290000E+02 5.813586E+02 -4.370480E-02 5.195463E+02 5.730000E+02 5.698862E+02 -6.046956E-02 5.196651E+02 5.700000E+02 5.602208E+02 -7.454535E-02 5.197839E+02 5.590000E+02 5.644666E+02 -6.779490E-02 5.199026E+02 5.660000E+02 5.673527E+02 -6.307860E-02 5.200214E+02 5.680000E+02 5.913011E+02 -2.679005E-02 5.201402E+02 5.960000E+02 6.412435E+02 4.849549E-02 5.202590E+02 6.500000E+02 6.187037E+02 1.511709E-02 5.203777E+02 6.130000E+02 5.976785E+02 -1.600492E-02 5.204965E+02 5.950000E+02 6.031762E+02 -7.341552E-03 5.206153E+02 6.050000E+02 6.029977E+02 -7.197327E-03 5.207341E+02 6.030000E+02 5.757549E+02 -4.770248E-02 5.208528E+02 5.710000E+02 5.978229E+02 -1.414390E-02 5.209716E+02 6.030000E+02 6.165851E+02 1.446395E-02 5.210904E+02 6.190000E+02 5.865174E+02 -3.032593E-02 5.212092E+02 5.800000E+02 6.122187E+02 8.738573E-03 5.213279E+02 6.180000E+02 5.944894E+02 -1.752248E-02 5.214467E+02 5.900000E+02 6.050335E+02 -1.241288E-03 5.215655E+02 6.080000E+02 5.867308E+02 -2.838630E-02 5.216843E+02 5.830000E+02 6.340549E+02 4.329931E-02 5.218030E+02 6.440000E+02 6.141907E+02 1.379379E-02 5.219218E+02 6.090000E+02 5.901589E+02 -2.200621E-02 5.220406E+02 5.870000E+02 6.045490E+02 9.900739E-05 5.221594E+02 6.080000E+02 6.030474E+02 -1.753826E-03 5.222781E+02 6.020000E+02 5.846357E+02 -2.912031E-02 5.223969E+02 5.810000E+02 6.257281E+02 3.330766E-02 5.225157E+02 6.340000E+02 6.262691E+02 3.454512E-02 5.226345E+02 6.250000E+02 5.976373E+02 -8.274370E-03 5.227532E+02 5.930000E+02 5.916032E+02 -1.697860E-02 5.228720E+02 5.920000E+02 6.082413E+02 8.576429E-03 5.229908E+02 6.120000E+02 6.240062E+02 3.282688E-02 5.231096E+02 6.270000E+02 6.357051E+02 5.094463E-02 5.232283E+02 6.380000E+02 6.065421E+02 7.249120E-03 5.233471E+02 6.010000E+02 6.017969E+02 4.849272E-04 5.234659E+02 6.020000E+02 6.350427E+02 5.123483E-02 5.235847E+02 6.410000E+02 5.966673E+02 -6.462844E-03 5.237034E+02 5.880000E+02 6.228163E+02 3.357098E-02 5.238222E+02 6.290000E+02 6.133394E+02 1.962723E-02 5.239410E+02 6.100000E+02 6.011710E+02 1.597732E-03 5.240598E+02 5.990000E+02 5.903105E+02 -1.446173E-02 5.241785E+02 5.880000E+02 6.206999E+02 3.205427E-02 5.242973E+02 6.260000E+02 5.922550E+02 -1.069969E-02 5.244161E+02 5.850000E+02 5.923871E+02 -1.008824E-02 5.245349E+02 5.930000E+02 5.741535E+02 -3.737536E-02 5.246536E+02 5.700000E+02 5.914214E+02 -1.073904E-02 5.247724E+02 5.950000E+02 5.995310E+02 1.991719E-03 5.248912E+02 6.000000E+02 5.985977E+02 9.836627E-04 5.250099E+02 5.980000E+02 5.898227E+02 -1.195172E-02 5.251287E+02 5.880000E+02 6.024617E+02 7.685458E-03 5.252475E+02 6.050000E+02 5.705285E+02 -4.050583E-02 5.253663E+02 5.640000E+02 5.874914E+02 -1.427956E-02 5.254850E+02 5.920000E+02 5.834487E+02 -2.003409E-02 5.256038E+02 5.820000E+02 6.138919E+02 2.675286E-02 5.257226E+02 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6.350000E+02 5.662067E+02 -3.053960E-02 5.303548E+02 6.090000E+02 5.424977E+02 -6.676690E-02 5.304736E+02 6.120000E+02 5.515196E+02 -5.244217E-02 5.305923E+02 6.510000E+02 6.119865E+02 4.141521E-02 5.307111E+02 7.390000E+02 6.066353E+02 3.355274E-02 5.308299E+02 7.340000E+02 5.520797E+02 -5.042253E-02 5.309487E+02 6.750000E+02 5.985497E+02 2.187870E-02 5.310674E+02 7.330000E+02 5.747999E+02 -1.447973E-02 5.311862E+02 6.780000E+02 5.430516E+02 -6.323975E-02 5.313050E+02 6.270000E+02 5.995850E+02 2.471629E-02 5.314238E+02 6.800000E+02 5.916776E+02 1.286906E-02 5.315425E+02 6.390000E+02 6.164131E+02 5.162095E-02 5.316613E+02 6.580000E+02 5.576085E+02 -3.914493E-02 5.317801E+02 5.710000E+02 6.122616E+02 4.602639E-02 5.318989E+02 6.420000E+02 6.043859E+02 3.421769E-02 5.320176E+02 6.130000E+02 6.279001E+02 7.113328E-02 5.321364E+02 6.420000E+02 6.546649E+02 1.131165E-01 5.322552E+02 6.650000E+02 6.406431E+02 9.177560E-02 5.323740E+02 6.420000E+02 6.675626E+02 1.340390E-01 5.324927E+02 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1.184830E+03 9.521880E-01 5.348682E+02 1.165000E+03 1.063784E+03 7.634872E-01 5.349870E+02 1.045000E+03 1.025076E+03 7.035579E-01 5.351058E+02 1.022000E+03 9.688965E+02 6.162192E-01 5.352245E+02 9.600000E+02 9.268238E+02 5.509227E-01 5.353433E+02 9.210000E+02 8.571186E+02 4.422759E-01 5.354621E+02 8.450000E+02 8.767630E+02 4.736273E-01 5.355809E+02 8.840000E+02 8.779320E+02 4.760171E-01 5.356996E+02 8.780000E+02 8.691277E+02 4.627667E-01 5.358184E+02 8.690000E+02 8.296142E+02 4.013165E-01 5.359372E+02 8.240000E+02 8.619468E+02 4.526104E-01 5.360560E+02 8.700000E+02 7.970527E+02 3.512540E-01 5.361747E+02 7.850000E+02 7.870421E+02 3.360535E-01 5.362935E+02 7.880000E+02 7.750690E+02 3.177509E-01 5.364123E+02 7.740000E+02 7.432088E+02 2.681762E-01 5.365311E+02 7.390000E+02 7.687906E+02 3.088942E-01 5.366498E+02 7.770000E+02 7.742494E+02 3.179801E-01 5.367686E+02 7.750000E+02 7.336401E+02 2.545860E-01 5.368874E+02 7.280000E+02 7.961946E+02 3.535378E-01 5.370062E+02 8.120000E+02 7.487745E+02 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